Mechanically induced pyrogallol[4]arene hexamer assembly in the solid state extends the scope of molecular encapsulationElectronic supplementary information (ESI) available: Experimental procedures, NMR spectra, and tabulated data. See DOI: 10.1039/c7sc03821f
Pyrogallol[4]arene hexamers are hydrogen-bonded molecular capsules of exceptional kinetic stability that can entrap small molecule guests indefinitely, without exchange, at ambient temperatures. Here, we report on the use of a ball mill to induce self-assembly of the capsule components and the guest...
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