Unveiling the role of boroxines in metal-free carbon-carbon homologations using diazo compounds and boronic acidsElectronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02264f, additional data is available from the University of Cambridge Data Repository Website: https://doi.org/10.17863/CAM.10823

By means of computational and experimental mechanistic studies the fundamental role of boroxines in the reaction between diazo compounds and boronic acids was elucidated. Consequently, a selective metal-free carbon-carbon homologation of aryl and vinyl boroxines using TMSCHN 2 , giving access to TMS...

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Hauptverfasser: Bomio, Claudio, Kabeshov, Mikhail A, Lit, Arthur R, Lau, Shing-Hing, Ehlert, Janna, Battilocchio, Claudio, Ley, Steven V
Format: Artikel
Sprache:eng
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