A pillared-layered copper(i) halide-based metal-organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shiftElectronic supplementary information (ESI) available: The bond lengths, IR spectra and TG curve. CCDC 967744 and 967745. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7ra11950j
We report a new copper halide-based compound [Cu 6 I 6 Br 2 C 16 H 32 N 4 ] ( 1 ) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound 1 shows dual emission at ca. 500 nm and ca. 530 nm. As the temperature decreased from 300 K down to 6 K, the luminesc...
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| container_end_page | 1978 |
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| container_issue | 4 |
| container_start_page | 1973 |
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| container_volume | 8 |
| creator | Xin, Bingjing Sang, Jianwei Gao, Yi Li, Guanghua Shi, Zhan Feng, Shouhua |
| description | We report a new copper halide-based compound [Cu
6
I
6
Br
2
C
16
H
32
N
4
] (
1
) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound
1
shows dual emission at
ca.
500 nm and
ca.
530 nm. As the temperature decreased from 300 K down to 6 K, the luminescent properties of compound
1
show large red shifts of 120 nm and 72 nm, respectively.
A pillared-layered copper(
i
) halide-based metal-organic framework [Cu
6
I
6
Br
2
C
16
H
32
N
4
] exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift is reported. |
| doi_str_mv | 10.1039/c7ra11950j |
| format | Article |
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6
I
6
Br
2
C
16
H
32
N
4
] (
1
) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound
1
shows dual emission at
ca.
500 nm and
ca.
530 nm. As the temperature decreased from 300 K down to 6 K, the luminescent properties of compound
1
show large red shifts of 120 nm and 72 nm, respectively.
A pillared-layered copper(
i
) halide-based metal-organic framework [Cu
6
I
6
Br
2
C
16
H
32
N
4
] exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift is reported.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c7ra11950j</identifier><language>eng</language><creationdate>2018-01</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,860,27903,27904</link.rule.ids></links><search><creatorcontrib>Xin, Bingjing</creatorcontrib><creatorcontrib>Sang, Jianwei</creatorcontrib><creatorcontrib>Gao, Yi</creatorcontrib><creatorcontrib>Li, Guanghua</creatorcontrib><creatorcontrib>Shi, Zhan</creatorcontrib><creatorcontrib>Feng, Shouhua</creatorcontrib><title>A pillared-layered copper(i) halide-based metal-organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shiftElectronic supplementary information (ESI) available: The bond lengths, IR spectra and TG curve. CCDC 967744 and 967745. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7ra11950j</title><description>We report a new copper halide-based compound [Cu
6
I
6
Br
2
C
16
H
32
N
4
] (
1
) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound
1
shows dual emission at
ca.
500 nm and
ca.
530 nm. As the temperature decreased from 300 K down to 6 K, the luminescent properties of compound
1
show large red shifts of 120 nm and 72 nm, respectively.
A pillared-layered copper(
i
) halide-based metal-organic framework [Cu
6
I
6
Br
2
C
16
H
32
N
4
] exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift is reported.</description><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkT9PwzAQxQMSEghY2JGODSRSkv5JVTYUWuiEBN2ra3KJXezYOrtA-SJ8XZyC6IAEXs569_z8OzuKTtKkkya90VUxZEzT0SBZ7kYH3aSfxd0kG-1Hx84tk7CyQdrN0oOdjxuwUilkKmOFawoVCmMt8bm8AIFKlhQv0AVZk0cVG66xkQVUjJpeDT8DvQm5kF42NZQrVEBaOidNcwnYlCGd3k0h2OhwqBW8INY_imUT7vKSHLxKLwAhsNQEnnTQ0a-Y4pIsNSU1_icaWlwnZOXHigrPpiVyK2sV6eBDXoNsKsMafes-Hz9NLwBfUCpcKLqGmSBYmACjqKm9cJcwfQRn2yjcQM7uoFjxC3Ugz29zGGXDYb-_6Wy2gw5MDEOI3WgFr114G2VqRisCSokeAwHk0wkEn2lnBtqifqGBI4Lbh-k1_P61o2ivQuXo-LseRqeT8Sy_j9kVc8tShxnnW3vvMDr7qz-3ZdX7L-MTo3e83A</recordid><startdate>20180108</startdate><enddate>20180108</enddate><creator>Xin, Bingjing</creator><creator>Sang, Jianwei</creator><creator>Gao, Yi</creator><creator>Li, Guanghua</creator><creator>Shi, Zhan</creator><creator>Feng, Shouhua</creator><scope/></search><sort><creationdate>20180108</creationdate><title>A pillared-layered copper(i) halide-based metal-organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shiftElectronic supplementary information (ESI) available: The bond lengths, IR spectra and TG curve. CCDC 967744 and 967745. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7ra11950j</title><author>Xin, Bingjing ; Sang, Jianwei ; Gao, Yi ; Li, Guanghua ; Shi, Zhan ; Feng, Shouhua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7ra11950j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xin, Bingjing</creatorcontrib><creatorcontrib>Sang, Jianwei</creatorcontrib><creatorcontrib>Gao, Yi</creatorcontrib><creatorcontrib>Li, Guanghua</creatorcontrib><creatorcontrib>Shi, Zhan</creatorcontrib><creatorcontrib>Feng, Shouhua</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xin, Bingjing</au><au>Sang, Jianwei</au><au>Gao, Yi</au><au>Li, Guanghua</au><au>Shi, Zhan</au><au>Feng, Shouhua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A pillared-layered copper(i) halide-based metal-organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shiftElectronic supplementary information (ESI) available: The bond lengths, IR spectra and TG curve. CCDC 967744 and 967745. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7ra11950j</atitle><date>2018-01-08</date><risdate>2018</risdate><volume>8</volume><issue>4</issue><spage>1973</spage><epage>1978</epage><pages>1973-1978</pages><eissn>2046-2069</eissn><abstract>We report a new copper halide-based compound [Cu
6
I
6
Br
2
C
16
H
32
N
4
] (
1
) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound
1
shows dual emission at
ca.
500 nm and
ca.
530 nm. As the temperature decreased from 300 K down to 6 K, the luminescent properties of compound
1
show large red shifts of 120 nm and 72 nm, respectively.
A pillared-layered copper(
i
) halide-based metal-organic framework [Cu
6
I
6
Br
2
C
16
H
32
N
4
] exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift is reported.</abstract><doi>10.1039/c7ra11950j</doi><tpages>6</tpages></addata></record> |
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| language | eng |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central |
| title | A pillared-layered copper(i) halide-based metal-organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shiftElectronic supplementary information (ESI) available: The bond lengths, IR spectra and TG curve. CCDC 967744 and 967745. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7ra11950j |
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