Transition from smectic nanofibers to smectic vesicles in the self-assemblies of PEG-b-liquid crystal polycarbonatesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7py01131h

This work reports on the self-assemblies of amphiphilic biodegradable cholesterol-containing block copolymers PEG- b -PMCC. The polymers are prepared through the ring opening polymerization (ROP) of a methyl and cholesteryl substituted trimethylenecarbonate monomer (MCC). They can self-assemble into...

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Hauptverfasser: Zhou, Lu, Zhang, Dapeng, Hocine, Sabrina, Pilone, Alessia, Trépout, Sylvain, Marco, Sergio, Thomas, Christophe, Guo, Jia, Li, Min-Hui
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container_issue 33
container_start_page 4776
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creator Zhou, Lu
Zhang, Dapeng
Hocine, Sabrina
Pilone, Alessia
Trépout, Sylvain
Marco, Sergio
Thomas, Christophe
Guo, Jia
Li, Min-Hui
description This work reports on the self-assemblies of amphiphilic biodegradable cholesterol-containing block copolymers PEG- b -PMCC. The polymers are prepared through the ring opening polymerization (ROP) of a methyl and cholesteryl substituted trimethylenecarbonate monomer (MCC). They can self-assemble into smectic ellipsoidal vesicles in water through the transition from smectic nanofibers. A transition from nanofibers to ellipsoidal vesicles through lamellas was evidenced as the self-assembling mechanism for biodegradable smectic polycarbonate-based amphiphilic block copolymers.
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title Transition from smectic nanofibers to smectic vesicles in the self-assemblies of PEG-b-liquid crystal polycarbonatesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7py01131h
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