A 3D interconnected NH4Fe0.6V2.4O7.4@C nanocomposite with superior sodium storage propertiesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7nr09146j
A novel 3D interconnected NH 4 Fe 0.6 V 2.4 O 7.4 @C nanocomposite was in situ synthesized through a facile hydrothermal reaction at low temperature (98 °C), and its electrochemical performance as a cathode for sodium-ion batteries (SIBs) was investigated for the first time. Under the intercalation...
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| creator | Xiong, Zhenmin Chen, Lei Zhao, Long Zhao, Yanming Feng, Jingjie Huang, Chun mao Dong, Youzhong Zhang, Hui Wang, Yang Kuang, Quan Fan, Qinghua Liu, Shenghong Chen, Siyuan |
| description | A novel 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite was
in situ
synthesized through a facile hydrothermal reaction at low temperature (98 °C), and its electrochemical performance as a cathode for sodium-ion batteries (SIBs) was investigated for the first time. Under the intercalation of Fe
3+
and carbon-coating, as-prepared samples turned to 3D interconnected structures, which were composed of NH
4
Fe
0.6
V
2.4
O
7.4
nanoparticles and carbon chains. The 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C nanocomposite exhibits a high discharge specific capacity of 306 mA h g
−1
at a current density of 20 mA g
−1
and a high-rate capacity of 130 mA h g
−1
at 0.4 A g
−1
. The results of EIS and
ex situ
SEM indicated that the 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C nanocomposite possesses good electrical conductivity and structural stability. The
ex situ
XRD results suggest that NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C undergoes a reversible insertion/de-insertion mechanism during a charge/discharge process. Our work demonstrates that the 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite material could be considered as a potential cathode for sodium ion batteries.
A novel 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite was
in situ
synthesized through a facile hydrothermal reaction at low temperature (98 °C), and its electrochemical performance as a cathode for sodium-ion batteries (SIBs) was investigated for the first time. |
| doi_str_mv | 10.1039/c7nr09146j |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c7nr09146j</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c7nr09146j</sourcerecordid><originalsourceid>FETCH-rsc_primary_c7nr09146j3</originalsourceid><addsrcrecordid>eNqFj0FLw0AUhBdRsFYv3oXnTQ-Nm-ySEE9Km9Je7KHiNaybF92S7Ft2t4o_yv9oBNGD0J5mYIZvGMbOU56kXJQ3urCel6nMNwdslHHJJ0IU2eGvz-UxOwlhw3leilyM2Oc9iBkYG9FrshZ1xAYeFnKOPMmfskSuikTeTcEqS5p6R8FEhHcTXyFsHXpDHgI1ZttDiOTVC4LzNATRYKi6gefJGv1ddh32aKPyH8NeS75X0ZCFq2q9vAb1pkynnjtMYI0Is9XyFv6fOmVHreoCnv3omF3Mq8fpYuKDrp03_QCv_-pizC535bVrWrGP8QXXN2qI</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A 3D interconnected NH4Fe0.6V2.4O7.4@C nanocomposite with superior sodium storage propertiesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7nr09146j</title><source>Royal Society Of Chemistry Journals</source><creator>Xiong, Zhenmin ; Chen, Lei ; Zhao, Long ; Zhao, Yanming ; Feng, Jingjie ; Huang, Chun mao ; Dong, Youzhong ; Zhang, Hui ; Wang, Yang ; Kuang, Quan ; Fan, Qinghua ; Liu, Shenghong ; Chen, Siyuan</creator><creatorcontrib>Xiong, Zhenmin ; Chen, Lei ; Zhao, Long ; Zhao, Yanming ; Feng, Jingjie ; Huang, Chun mao ; Dong, Youzhong ; Zhang, Hui ; Wang, Yang ; Kuang, Quan ; Fan, Qinghua ; Liu, Shenghong ; Chen, Siyuan</creatorcontrib><description>A novel 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite was
in situ
synthesized through a facile hydrothermal reaction at low temperature (98 °C), and its electrochemical performance as a cathode for sodium-ion batteries (SIBs) was investigated for the first time. Under the intercalation of Fe
3+
and carbon-coating, as-prepared samples turned to 3D interconnected structures, which were composed of NH
4
Fe
0.6
V
2.4
O
7.4
nanoparticles and carbon chains. The 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C nanocomposite exhibits a high discharge specific capacity of 306 mA h g
−1
at a current density of 20 mA g
−1
and a high-rate capacity of 130 mA h g
−1
at 0.4 A g
−1
. The results of EIS and
ex situ
SEM indicated that the 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C nanocomposite possesses good electrical conductivity and structural stability. The
ex situ
XRD results suggest that NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C undergoes a reversible insertion/de-insertion mechanism during a charge/discharge process. Our work demonstrates that the 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite material could be considered as a potential cathode for sodium ion batteries.
A novel 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite was
in situ
synthesized through a facile hydrothermal reaction at low temperature (98 °C), and its electrochemical performance as a cathode for sodium-ion batteries (SIBs) was investigated for the first time.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c7nr09146j</identifier><language>eng</language><creationdate>2018-04</creationdate><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27928,27929</link.rule.ids></links><search><creatorcontrib>Xiong, Zhenmin</creatorcontrib><creatorcontrib>Chen, Lei</creatorcontrib><creatorcontrib>Zhao, Long</creatorcontrib><creatorcontrib>Zhao, Yanming</creatorcontrib><creatorcontrib>Feng, Jingjie</creatorcontrib><creatorcontrib>Huang, Chun mao</creatorcontrib><creatorcontrib>Dong, Youzhong</creatorcontrib><creatorcontrib>Zhang, Hui</creatorcontrib><creatorcontrib>Wang, Yang</creatorcontrib><creatorcontrib>Kuang, Quan</creatorcontrib><creatorcontrib>Fan, Qinghua</creatorcontrib><creatorcontrib>Liu, Shenghong</creatorcontrib><creatorcontrib>Chen, Siyuan</creatorcontrib><title>A 3D interconnected NH4Fe0.6V2.4O7.4@C nanocomposite with superior sodium storage propertiesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7nr09146j</title><description>A novel 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite was
in situ
synthesized through a facile hydrothermal reaction at low temperature (98 °C), and its electrochemical performance as a cathode for sodium-ion batteries (SIBs) was investigated for the first time. Under the intercalation of Fe
3+
and carbon-coating, as-prepared samples turned to 3D interconnected structures, which were composed of NH
4
Fe
0.6
V
2.4
O
7.4
nanoparticles and carbon chains. The 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C nanocomposite exhibits a high discharge specific capacity of 306 mA h g
−1
at a current density of 20 mA g
−1
and a high-rate capacity of 130 mA h g
−1
at 0.4 A g
−1
. The results of EIS and
ex situ
SEM indicated that the 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C nanocomposite possesses good electrical conductivity and structural stability. The
ex situ
XRD results suggest that NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C undergoes a reversible insertion/de-insertion mechanism during a charge/discharge process. Our work demonstrates that the 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite material could be considered as a potential cathode for sodium ion batteries.
A novel 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite was
in situ
synthesized through a facile hydrothermal reaction at low temperature (98 °C), and its electrochemical performance as a cathode for sodium-ion batteries (SIBs) was investigated for the first time.</description><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFj0FLw0AUhBdRsFYv3oXnTQ-Nm-ySEE9Km9Je7KHiNaybF92S7Ft2t4o_yv9oBNGD0J5mYIZvGMbOU56kXJQ3urCel6nMNwdslHHJJ0IU2eGvz-UxOwlhw3leilyM2Oc9iBkYG9FrshZ1xAYeFnKOPMmfskSuikTeTcEqS5p6R8FEhHcTXyFsHXpDHgI1ZttDiOTVC4LzNATRYKi6gefJGv1ddh32aKPyH8NeS75X0ZCFq2q9vAb1pkynnjtMYI0Is9XyFv6fOmVHreoCnv3omF3Mq8fpYuKDrp03_QCv_-pizC535bVrWrGP8QXXN2qI</recordid><startdate>20180419</startdate><enddate>20180419</enddate><creator>Xiong, Zhenmin</creator><creator>Chen, Lei</creator><creator>Zhao, Long</creator><creator>Zhao, Yanming</creator><creator>Feng, Jingjie</creator><creator>Huang, Chun mao</creator><creator>Dong, Youzhong</creator><creator>Zhang, Hui</creator><creator>Wang, Yang</creator><creator>Kuang, Quan</creator><creator>Fan, Qinghua</creator><creator>Liu, Shenghong</creator><creator>Chen, Siyuan</creator><scope/></search><sort><creationdate>20180419</creationdate><title>A 3D interconnected NH4Fe0.6V2.4O7.4@C nanocomposite with superior sodium storage propertiesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7nr09146j</title><author>Xiong, Zhenmin ; Chen, Lei ; Zhao, Long ; Zhao, Yanming ; Feng, Jingjie ; Huang, Chun mao ; Dong, Youzhong ; Zhang, Hui ; Wang, Yang ; Kuang, Quan ; Fan, Qinghua ; Liu, Shenghong ; Chen, Siyuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7nr09146j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Xiong, Zhenmin</creatorcontrib><creatorcontrib>Chen, Lei</creatorcontrib><creatorcontrib>Zhao, Long</creatorcontrib><creatorcontrib>Zhao, Yanming</creatorcontrib><creatorcontrib>Feng, Jingjie</creatorcontrib><creatorcontrib>Huang, Chun mao</creatorcontrib><creatorcontrib>Dong, Youzhong</creatorcontrib><creatorcontrib>Zhang, Hui</creatorcontrib><creatorcontrib>Wang, Yang</creatorcontrib><creatorcontrib>Kuang, Quan</creatorcontrib><creatorcontrib>Fan, Qinghua</creatorcontrib><creatorcontrib>Liu, Shenghong</creatorcontrib><creatorcontrib>Chen, Siyuan</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiong, Zhenmin</au><au>Chen, Lei</au><au>Zhao, Long</au><au>Zhao, Yanming</au><au>Feng, Jingjie</au><au>Huang, Chun mao</au><au>Dong, Youzhong</au><au>Zhang, Hui</au><au>Wang, Yang</au><au>Kuang, Quan</au><au>Fan, Qinghua</au><au>Liu, Shenghong</au><au>Chen, Siyuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A 3D interconnected NH4Fe0.6V2.4O7.4@C nanocomposite with superior sodium storage propertiesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7nr09146j</atitle><date>2018-04-19</date><risdate>2018</risdate><volume>1</volume><issue>15</issue><spage>6992</spage><epage>71</epage><pages>6992-71</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>A novel 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite was
in situ
synthesized through a facile hydrothermal reaction at low temperature (98 °C), and its electrochemical performance as a cathode for sodium-ion batteries (SIBs) was investigated for the first time. Under the intercalation of Fe
3+
and carbon-coating, as-prepared samples turned to 3D interconnected structures, which were composed of NH
4
Fe
0.6
V
2.4
O
7.4
nanoparticles and carbon chains. The 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C nanocomposite exhibits a high discharge specific capacity of 306 mA h g
−1
at a current density of 20 mA g
−1
and a high-rate capacity of 130 mA h g
−1
at 0.4 A g
−1
. The results of EIS and
ex situ
SEM indicated that the 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C nanocomposite possesses good electrical conductivity and structural stability. The
ex situ
XRD results suggest that NH
4
Fe
0.6
V
2.4
O
7.4
@0.5 wt%C undergoes a reversible insertion/de-insertion mechanism during a charge/discharge process. Our work demonstrates that the 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite material could be considered as a potential cathode for sodium ion batteries.
A novel 3D interconnected NH
4
Fe
0.6
V
2.4
O
7.4
@C nanocomposite was
in situ
synthesized through a facile hydrothermal reaction at low temperature (98 °C), and its electrochemical performance as a cathode for sodium-ion batteries (SIBs) was investigated for the first time.</abstract><doi>10.1039/c7nr09146j</doi><tpages>1</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals |
| title | A 3D interconnected NH4Fe0.6V2.4O7.4@C nanocomposite with superior sodium storage propertiesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7nr09146j |
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