MnCo2O4 spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditionsElectronic supplementary information (ESI) available: Catalyst preparation, characterization - figures (NH3-TPD, TEM, TEM-EDS, XPS, and XRD) and tables (EDS, BET, CO chemisorption, and ICP-AES), & FDCA purification - 1H- and 13C-NMR of purified FDCA. See DOI: 10.1039/c7gc00027h
A new class of MnCo 2 O 4 spinel supported Ru catalyst, Ru/MnCo 2 O 4 , was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water. The catalyst Ru/MnCo 2 O 4 having both Lewis and Brønsted acidic active sites greatly enhanced the FDCA yield. The catalyst...
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| creator | Mishra, Dinesh Kumar Lee, Hye Jin Kim, Jinsung Lee, Hong-Shik Cho, Jin Ku Suh, Young-Woong Yi, Yongjin Kim, Yong Jin |
| description | A new class of MnCo
2
O
4
spinel supported Ru catalyst, Ru/MnCo
2
O
4
, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water. The catalyst Ru/MnCo
2
O
4
having both Lewis and Brønsted acidic active sites greatly enhanced the FDCA yield. The catalyst was recyclable up to five successive runs without considerable loss of its original activity.
A new class of MnCo
2
O
4
spinel supported Ru catalyst, Ru/MnCo
2
O
4
, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water. |
| doi_str_mv | 10.1039/c7gc00027h |
| format | Article |
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2
O
4
spinel supported Ru catalyst, Ru/MnCo
2
O
4
, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water. The catalyst Ru/MnCo
2
O
4
having both Lewis and Brønsted acidic active sites greatly enhanced the FDCA yield. The catalyst was recyclable up to five successive runs without considerable loss of its original activity.
A new class of MnCo
2
O
4
spinel supported Ru catalyst, Ru/MnCo
2
O
4
, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/c7gc00027h</identifier><language>eng</language><creationdate>2017-04</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Mishra, Dinesh Kumar</creatorcontrib><creatorcontrib>Lee, Hye Jin</creatorcontrib><creatorcontrib>Kim, Jinsung</creatorcontrib><creatorcontrib>Lee, Hong-Shik</creatorcontrib><creatorcontrib>Cho, Jin Ku</creatorcontrib><creatorcontrib>Suh, Young-Woong</creatorcontrib><creatorcontrib>Yi, Yongjin</creatorcontrib><creatorcontrib>Kim, Yong Jin</creatorcontrib><title>MnCo2O4 spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditionsElectronic supplementary information (ESI) available: Catalyst preparation, characterization - figures (NH3-TPD, TEM, TEM-EDS, XPS, and XRD) and tables (EDS, BET, CO chemisorption, and ICP-AES), & FDCA purification - 1H- and 13C-NMR of purified FDCA. See DOI: 10.1039/c7gc00027h</title><description>A new class of MnCo
2
O
4
spinel supported Ru catalyst, Ru/MnCo
2
O
4
, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water. The catalyst Ru/MnCo
2
O
4
having both Lewis and Brønsted acidic active sites greatly enhanced the FDCA yield. The catalyst was recyclable up to five successive runs without considerable loss of its original activity.
A new class of MnCo
2
O
4
spinel supported Ru catalyst, Ru/MnCo
2
O
4
, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water.</description><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkT1PwzAQhgMCic-FHelYEJViSJqqFWwlSdUOpRXtwFYZ50KNEtvYDgL-BH8ZJ-FjQILFfqV77t7za887CoPzMIguL9jggQVB0B2sN73dsNePyGV3EGx96353x9sz5jEIwnDQ7-1uvE9FLLuzHhjFBRZgKqWktpiBruwaBa9KYNTS4tVYyKUGyjWRLzyjlksBMofxdARWwiiJh1CJDB3yVKGsDKg1NQhUZHDvBMk1IjApMl63mrRAZrUUnDWmBZYoLNWvwIXzKdv5Z-li0gH6THlB7wu8gvhrF6VRUd1QPrC1k8yi5m9tH4GcP1QaDZzdjCOynCc-LNNpc5A0WfhwN3dHvdvdbdJphK0dXENTvk6XPsQzNxlLbqRWrVHNTeI5GaaLjg-n7atVpXnO2ZdzOCYNF0YxuZne1hm1hAu15s9h4YJIZpMr-P1tB952TguDh5_3vnc8SpfxmGjDVkrz0iW0-sGjfe_kr_pKZXn034wPifGymw</recordid><startdate>20170403</startdate><enddate>20170403</enddate><creator>Mishra, Dinesh Kumar</creator><creator>Lee, Hye Jin</creator><creator>Kim, Jinsung</creator><creator>Lee, Hong-Shik</creator><creator>Cho, Jin Ku</creator><creator>Suh, Young-Woong</creator><creator>Yi, Yongjin</creator><creator>Kim, Yong Jin</creator><scope/></search><sort><creationdate>20170403</creationdate><title>MnCo2O4 spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditionsElectronic supplementary information (ESI) available: Catalyst preparation, characterization - figures (NH3-TPD, TEM, TEM-EDS, XPS, and XRD) and tables (EDS, BET, CO chemisorption, and ICP-AES), & FDCA purification - 1H- and 13C-NMR of purified FDCA. See DOI: 10.1039/c7gc00027h</title><author>Mishra, Dinesh Kumar ; Lee, Hye Jin ; Kim, Jinsung ; Lee, Hong-Shik ; Cho, Jin Ku ; Suh, Young-Woong ; Yi, Yongjin ; Kim, Yong Jin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7gc00027h3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mishra, Dinesh Kumar</creatorcontrib><creatorcontrib>Lee, Hye Jin</creatorcontrib><creatorcontrib>Kim, Jinsung</creatorcontrib><creatorcontrib>Lee, Hong-Shik</creatorcontrib><creatorcontrib>Cho, Jin Ku</creatorcontrib><creatorcontrib>Suh, Young-Woong</creatorcontrib><creatorcontrib>Yi, Yongjin</creatorcontrib><creatorcontrib>Kim, Yong Jin</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mishra, Dinesh Kumar</au><au>Lee, Hye Jin</au><au>Kim, Jinsung</au><au>Lee, Hong-Shik</au><au>Cho, Jin Ku</au><au>Suh, Young-Woong</au><au>Yi, Yongjin</au><au>Kim, Yong Jin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>MnCo2O4 spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditionsElectronic supplementary information (ESI) available: Catalyst preparation, characterization - figures (NH3-TPD, TEM, TEM-EDS, XPS, and XRD) and tables (EDS, BET, CO chemisorption, and ICP-AES), & FDCA purification - 1H- and 13C-NMR of purified FDCA. See DOI: 10.1039/c7gc00027h</atitle><date>2017-04-03</date><risdate>2017</risdate><volume>19</volume><issue>7</issue><spage>1619</spage><epage>1623</epage><pages>1619-1623</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>A new class of MnCo
2
O
4
spinel supported Ru catalyst, Ru/MnCo
2
O
4
, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water. The catalyst Ru/MnCo
2
O
4
having both Lewis and Brønsted acidic active sites greatly enhanced the FDCA yield. The catalyst was recyclable up to five successive runs without considerable loss of its original activity.
A new class of MnCo
2
O
4
spinel supported Ru catalyst, Ru/MnCo
2
O
4
, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water.</abstract><doi>10.1039/c7gc00027h</doi><tpages>5</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | MnCo2O4 spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditionsElectronic supplementary information (ESI) available: Catalyst preparation, characterization - figures (NH3-TPD, TEM, TEM-EDS, XPS, and XRD) and tables (EDS, BET, CO chemisorption, and ICP-AES), & FDCA purification - 1H- and 13C-NMR of purified FDCA. See DOI: 10.1039/c7gc00027h |
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