Rotaxane synthesis exploiting the M(i)/M(iii) redox coupleElectronic supplementary information (ESI) available: 1H, 13C{1H} and 31P{1H} NMR and ESI-MS spectra of new compounds and selected reactions. CCDC 1563158-1563164. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt02648j
In the context of advancing the use of metal-based building blocks for the construction of mechanically interlocked molecules, we herein describe the preparation of late transition metal containing [2]rotaxanes ( 1 ). Capture and subsequent retention of the interlocked assemblies are achieved by the...
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