Synthesis and characterization of 1′-(diphenylphosphino)-1-isocyanoferrocene, an organometallic ligand combining two different soft donor moieties, and its Group 11 metal complexesElectronic supplementary information (ESI) available: Selected crystallographic data, additional structural drawings and copies of the NMR spectra. CCDC 1558580-1558590. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt02336g
The development of a practical synthesis of 1′-(diphenylphosphino)-1-aminoferrocene ( 2 ) and its P-borane adduct ( 2B ) allowed the facile preparation of 1′-(diphenylphosphino)-1-isocyanoferrocene ( 1 ). This compound combining two specific soft-donor moieties was studied as a ligand for univalent...
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