The effects of transition-metal doping and chromophore anchoring on the photocurrent response of titanium-oxo-clustersElectronic supplementary information (ESI) available: The XRD, IR, NMR spectra and TG. CCDC 1546765 and 1497582-1497584 of 1 and 2-4. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt01603d

Titanium-oxo-clusters (TOCs), [Ti 6 O 4 (O i Pr) 10 (Cat) 2 (BA) 2 ] ( 1 ) and [Ti 12 M 2 O 10 (OEt) 22 (Cat) 2 (BA) 4 ] (M = Co, Mn, Ni, 2-4 ; H 2 Cat = catechol, HBA = benzoic acid) are prepared in one step in an in situ solvothermal synthesis. Cluster structures of 2-4 can be considered as two 1...

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Hauptverfasser: Yang, Shen, Su, Hu-Chao, Hou, Jin-Le, Luo, Wen, Zou, Dan-Hong, Zhu, Qin-Yu, Dai, Jie
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Sprache:eng
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