Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structureElectronic supplementary information (ESI) available. CCDC 1525907. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt01408b
Two fluorophosphates, BaMPO 4 F (M = Cu, Co), have been synthesized by a conventional hydrothermal method, and they crystallize in the orthorhombic system with the space group P 2 1 2 1 2 1 , exhibiting a tunnel structure built by distorted MO 4 F square-pyramids and PO 4 tetrahedra. The magnetic be...
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| creator | Qiu, Chaoqun He, Zhangzhen Cui, Meiyan Chen, Sihuai |
| description | Two fluorophosphates, BaMPO
4
F (M = Cu, Co), have been synthesized by a conventional hydrothermal method, and they crystallize in the orthorhombic system with the space group
P
2
1
2
1
2
1
, exhibiting a tunnel structure built by distorted MO
4
F square-pyramids and PO
4
tetrahedra. The magnetic behaviors of the two compounds are investigated by means of magnetic susceptibility, magnetization, and heat capacity measurements. The results indicate that BaCuPO
4
F exhibits a paramagnetic behavior down to 2 K, while BaCoPO
4
F undergoes long-range antiferromagnetic ordering at 11.3 K and short-range magnetic ordering at ∼22 K.
Fluorophosphates, BaMPO
4
F (M = Cu, Co), with a tunnel structure show different magnetic behaviors, in which BaCuPO
4
F exhibits a paramagnetic behavior down to 2 K, while BaCoPO
4
F undergoes long-range antiferromagnetic ordering at low temperature. |
| doi_str_mv | 10.1039/c7dt01408b |
| format | Article |
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4
F (M = Cu, Co), have been synthesized by a conventional hydrothermal method, and they crystallize in the orthorhombic system with the space group
P
2
1
2
1
2
1
, exhibiting a tunnel structure built by distorted MO
4
F square-pyramids and PO
4
tetrahedra. The magnetic behaviors of the two compounds are investigated by means of magnetic susceptibility, magnetization, and heat capacity measurements. The results indicate that BaCuPO
4
F exhibits a paramagnetic behavior down to 2 K, while BaCoPO
4
F undergoes long-range antiferromagnetic ordering at 11.3 K and short-range magnetic ordering at ∼22 K.
Fluorophosphates, BaMPO
4
F (M = Cu, Co), with a tunnel structure show different magnetic behaviors, in which BaCuPO
4
F exhibits a paramagnetic behavior down to 2 K, while BaCoPO
4
F undergoes long-range antiferromagnetic ordering at low temperature.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c7dt01408b</identifier><language>eng</language><creationdate>2017-06</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Qiu, Chaoqun</creatorcontrib><creatorcontrib>He, Zhangzhen</creatorcontrib><creatorcontrib>Cui, Meiyan</creatorcontrib><creatorcontrib>Chen, Sihuai</creatorcontrib><title>Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structureElectronic supplementary information (ESI) available. CCDC 1525907. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt01408b</title><description>Two fluorophosphates, BaMPO
4
F (M = Cu, Co), have been synthesized by a conventional hydrothermal method, and they crystallize in the orthorhombic system with the space group
P
2
1
2
1
2
1
, exhibiting a tunnel structure built by distorted MO
4
F square-pyramids and PO
4
tetrahedra. The magnetic behaviors of the two compounds are investigated by means of magnetic susceptibility, magnetization, and heat capacity measurements. The results indicate that BaCuPO
4
F exhibits a paramagnetic behavior down to 2 K, while BaCoPO
4
F undergoes long-range antiferromagnetic ordering at 11.3 K and short-range magnetic ordering at ∼22 K.
Fluorophosphates, BaMPO
4
F (M = Cu, Co), with a tunnel structure show different magnetic behaviors, in which BaCuPO
4
F exhibits a paramagnetic behavior down to 2 K, while BaCoPO
4
F undergoes long-range antiferromagnetic ordering at low temperature.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkM1Lw0AQxaMoWKsXL56E8daCrZuPGit4MW2wh1Kh3ss02TQrm91ld2Lpf-_i50HQ0wzMb957M0FwFrJhyOLxdZGWxMKE3a73g06YpOlgHMXJwXcf3RwFx869MBZFbBR19s6XO0U1d8IBqhIa3ChOogBjteGWBHegK6CtBuG0I9sW1FqUUMlWe6TWztRInnrA-dMiyaE3h3vI2ivIdB-2gmpAoFYpLuFrnU8lL8hq5X1ca4zkDVeEdgdCVdo2SEIr6E2Xsz7gKwqJa8mHkGWTDMJRNBqzdAi5tuCJ99SF3TlCKfXGoqm9aomEXgyyWQ6e0_5CC_zH9cMFHOcwWczu4Pf7ToLDCqXjp5-1G1zk0-fscWBdsTJWND7u6gePu8HlX_OVKav4P4032g2OrA</recordid><startdate>20170606</startdate><enddate>20170606</enddate><creator>Qiu, Chaoqun</creator><creator>He, Zhangzhen</creator><creator>Cui, Meiyan</creator><creator>Chen, Sihuai</creator><scope/></search><sort><creationdate>20170606</creationdate><title>Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structureElectronic supplementary information (ESI) available. CCDC 1525907. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt01408b</title><author>Qiu, Chaoqun ; He, Zhangzhen ; Cui, Meiyan ; Chen, Sihuai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7dt01408b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qiu, Chaoqun</creatorcontrib><creatorcontrib>He, Zhangzhen</creatorcontrib><creatorcontrib>Cui, Meiyan</creatorcontrib><creatorcontrib>Chen, Sihuai</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qiu, Chaoqun</au><au>He, Zhangzhen</au><au>Cui, Meiyan</au><au>Chen, Sihuai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structureElectronic supplementary information (ESI) available. CCDC 1525907. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt01408b</atitle><date>2017-06-06</date><risdate>2017</risdate><volume>46</volume><issue>22</issue><spage>7261</spage><epage>7266</epage><pages>7261-7266</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Two fluorophosphates, BaMPO
4
F (M = Cu, Co), have been synthesized by a conventional hydrothermal method, and they crystallize in the orthorhombic system with the space group
P
2
1
2
1
2
1
, exhibiting a tunnel structure built by distorted MO
4
F square-pyramids and PO
4
tetrahedra. The magnetic behaviors of the two compounds are investigated by means of magnetic susceptibility, magnetization, and heat capacity measurements. The results indicate that BaCuPO
4
F exhibits a paramagnetic behavior down to 2 K, while BaCoPO
4
F undergoes long-range antiferromagnetic ordering at 11.3 K and short-range magnetic ordering at ∼22 K.
Fluorophosphates, BaMPO
4
F (M = Cu, Co), with a tunnel structure show different magnetic behaviors, in which BaCuPO
4
F exhibits a paramagnetic behavior down to 2 K, while BaCoPO
4
F undergoes long-range antiferromagnetic ordering at low temperature.</abstract><doi>10.1039/c7dt01408b</doi><tpages>6</tpages></addata></record> |
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| language | eng |
| recordid | cdi_rsc_primary_c7dt01408b |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Synthesis and magnetic properties of two isostructural fluorophosphates BaMPO4F (M = Cu, Co) with a tunnel structureElectronic supplementary information (ESI) available. CCDC 1525907. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt01408b |
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