Carboberyllation: addition of organoberyllium species to alkenes and alkynes. A comparison with carboborationElectronic supplementary information (ESI) available: Cartesian coordinates of optimized geometries, figures of optimized geometries. See DOI: 10.1039/c7dt01370a
The potential for carbometallation reactions between organoberyllium and model alkenes and alkynes has been investigated in a computational study. Results indicate that barriers for carbometallation reactions between BeR 2 and alkynes are as low as 100 kJ mol −1 , and much lower than corresponding r...
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