Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2Electronic supplementary information (ESI) available: Additional experimental data, copies of NMR and MS spectra, and further comments that are not central to the matter under discussion. See DOI: 10.1039/c7dt01019b
The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl] 2 in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex...
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| creator | Brazier, John B Newton, Mark A Barreiro, Elena M Adrio, Luis A Naya, Leticia Hii, King Kuok (Mimi) |
| description | The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]
2
in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex was tested for its catalytic activity in the coupling reaction between chlorobenzene and
n
-hexylamine, where different deactivation behaviours were observed in toluene, 1,4-dioxane and DMF.
The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]
2
in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. |
| doi_str_mv | 10.1039/c7dt01019b |
| format | Article |
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2
in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex was tested for its catalytic activity in the coupling reaction between chlorobenzene and
n
-hexylamine, where different deactivation behaviours were observed in toluene, 1,4-dioxane and DMF.
The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]
2
in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c7dt01019b</identifier><language>eng</language><creationdate>2017-06</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27933,27934</link.rule.ids></links><search><creatorcontrib>Brazier, John B</creatorcontrib><creatorcontrib>Newton, Mark A</creatorcontrib><creatorcontrib>Barreiro, Elena M</creatorcontrib><creatorcontrib>Adrio, Luis A</creatorcontrib><creatorcontrib>Naya, Leticia</creatorcontrib><creatorcontrib>Hii, King Kuok (Mimi)</creatorcontrib><title>Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2Electronic supplementary information (ESI) available: Additional experimental data, copies of NMR and MS spectra, and further comments that are not central to the matter under discussion. See DOI: 10.1039/c7dt01019b</title><description>The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]
2
in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex was tested for its catalytic activity in the coupling reaction between chlorobenzene and
n
-hexylamine, where different deactivation behaviours were observed in toluene, 1,4-dioxane and DMF.
The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]
2
in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFUE1LAzEQXUXB-nHxLoy3Vtq6H9XS3qRW7KFaXG8iJU1m3Ug2CUm22H_vbBE9CHrKZN6b995MFJ0mcT-Js9ElH4oQJ3EyWu1GrWQwHPZGaTbY-67T64Po0Pv3OE7T-Cpt7VzkRq1Rh55Ai1pQBbrmCpmTYdOFNzQVBrcBpgVwFpjaBMmB8SDXRABTwEs7X5TGdxaivSg7E_WaThXy4Iwmoq-tVViRLCMRqQvjKhak0dCe5rMOsDWTiq0UjuFGCNkgTAF-WHRyO6VAkGsXuLESfeP3MH_appnn4G1jRGjzL2oXSnTErJpJD6FkAZhD0CYAp5YjtWCoj0AhAnFr2tiBkJ7X3pN3H3JEuH2cjeH3RY-j_YIpjydf71F0djd9ntz3nOdLS3lpxeUPPfsfP_8LX1pRZJ-xJZgB</recordid><startdate>20170606</startdate><enddate>20170606</enddate><creator>Brazier, John B</creator><creator>Newton, Mark A</creator><creator>Barreiro, Elena M</creator><creator>Adrio, Luis A</creator><creator>Naya, Leticia</creator><creator>Hii, King Kuok (Mimi)</creator><scope/></search><sort><creationdate>20170606</creationdate><title>Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2Electronic supplementary information (ESI) available: Additional experimental data, copies of NMR and MS spectra, and further comments that are not central to the matter under discussion. See DOI: 10.1039/c7dt01019b</title><author>Brazier, John B ; Newton, Mark A ; Barreiro, Elena M ; Adrio, Luis A ; Naya, Leticia ; Hii, King Kuok (Mimi)</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7dt01019b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Brazier, John B</creatorcontrib><creatorcontrib>Newton, Mark A</creatorcontrib><creatorcontrib>Barreiro, Elena M</creatorcontrib><creatorcontrib>Adrio, Luis A</creatorcontrib><creatorcontrib>Naya, Leticia</creatorcontrib><creatorcontrib>Hii, King Kuok (Mimi)</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Brazier, John B</au><au>Newton, Mark A</au><au>Barreiro, Elena M</au><au>Adrio, Luis A</au><au>Naya, Leticia</au><au>Hii, King Kuok (Mimi)</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2Electronic supplementary information (ESI) available: Additional experimental data, copies of NMR and MS spectra, and further comments that are not central to the matter under discussion. See DOI: 10.1039/c7dt01019b</atitle><date>2017-06-06</date><risdate>2017</risdate><volume>46</volume><issue>22</issue><spage>7223</spage><epage>7231</epage><pages>7223-7231</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]
2
in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex was tested for its catalytic activity in the coupling reaction between chlorobenzene and
n
-hexylamine, where different deactivation behaviours were observed in toluene, 1,4-dioxane and DMF.
The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]
2
in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments.</abstract><doi>10.1039/c7dt01019b</doi><tpages>9</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2Electronic supplementary information (ESI) available: Additional experimental data, copies of NMR and MS spectra, and further comments that are not central to the matter under discussion. See DOI: 10.1039/c7dt01019b |
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