Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materialsElectronic supplementary information (ESI) available: Experimental procedures, crystallographic structures, FTIR spectroscopy, thermal analyses, PXRD patterns, and proton conductivity measurement for the title compounds. CCDC 1507115-1507117 and 1507119. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt00091j
Four lanthanide derivatives of Ta-containing POMs [Ln 3 (H 2 O) 22 ][P 2 W 15 Ta 3 O 62 ]· n H 2 O (Ln = La, 1 ; Ce, 2 ; Pr, 3 ; and Nd, 4 ) were isolated by the self-assembly of Wells-Dawson type Ta/W mixed-addendum POM and lanthanide ions. Compound 1 showed excellent proton conduction performance...
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| creator | Peng, Qingpo Li, Shujun Wang, Ruoya Liu, Shuxia Xie, Linhua Zhai, Jianxin Zhang, Jie Zhao, Qianyi Chen, Xuenian |
| description | Four lanthanide derivatives of Ta-containing POMs [Ln
3
(H
2
O)
22
][P
2
W
15
Ta
3
O
62
]·
n
H
2
O (Ln = La,
1
; Ce,
2
; Pr,
3
; and Nd,
4
) were isolated by the self-assembly of Wells-Dawson type Ta/W mixed-addendum POM and lanthanide ions. Compound
1
showed excellent proton conduction performance at high relative humidities (RHs), with conductivity reaching 1.26 × 10
−2
S cm
−1
at 95 °C under 98% RH.
Four lanthanide derivatives were isolated by the self-assembly of {P
2
W
15
Ta
3
O
62
} and lanthanide ions, which showed good proton conduction performance. |
| doi_str_mv | 10.1039/c7dt00091j |
| format | Article |
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3
(H
2
O)
22
][P
2
W
15
Ta
3
O
62
]·
n
H
2
O (Ln = La,
1
; Ce,
2
; Pr,
3
; and Nd,
4
) were isolated by the self-assembly of Wells-Dawson type Ta/W mixed-addendum POM and lanthanide ions. Compound
1
showed excellent proton conduction performance at high relative humidities (RHs), with conductivity reaching 1.26 × 10
−2
S cm
−1
at 95 °C under 98% RH.
Four lanthanide derivatives were isolated by the self-assembly of {P
2
W
15
Ta
3
O
62
} and lanthanide ions, which showed good proton conduction performance.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c7dt00091j</identifier><language>eng</language><creationdate>2017-03</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Peng, Qingpo</creatorcontrib><creatorcontrib>Li, Shujun</creatorcontrib><creatorcontrib>Wang, Ruoya</creatorcontrib><creatorcontrib>Liu, Shuxia</creatorcontrib><creatorcontrib>Xie, Linhua</creatorcontrib><creatorcontrib>Zhai, Jianxin</creatorcontrib><creatorcontrib>Zhang, Jie</creatorcontrib><creatorcontrib>Zhao, Qianyi</creatorcontrib><creatorcontrib>Chen, Xuenian</creatorcontrib><title>Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materialsElectronic supplementary information (ESI) available: Experimental procedures, crystallographic structures, FTIR spectroscopy, thermal analyses, PXRD patterns, and proton conductivity measurement for the title compounds. CCDC 1507115-1507117 and 1507119. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt00091j</title><description>Four lanthanide derivatives of Ta-containing POMs [Ln
3
(H
2
O)
22
][P
2
W
15
Ta
3
O
62
]·
n
H
2
O (Ln = La,
1
; Ce,
2
; Pr,
3
; and Nd,
4
) were isolated by the self-assembly of Wells-Dawson type Ta/W mixed-addendum POM and lanthanide ions. Compound
1
showed excellent proton conduction performance at high relative humidities (RHs), with conductivity reaching 1.26 × 10
−2
S cm
−1
at 95 °C under 98% RH.
Four lanthanide derivatives were isolated by the self-assembly of {P
2
W
15
Ta
3
O
62
} and lanthanide ions, which showed good proton conduction performance.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFUcFOGzEQ3VYgFSiX3itNbyCxwbshXYXrJhGRQCCI1N6iqT0hRl7bsp2I_Sp-kdmEwgEJTjOeefPmzXOW_ShErxD94amsVBJCDIuHr9lecVZV-bDsn-285uXvb9l-jA9ClKUYlHtfni7RpiVarQgUBb3GpNcUwS1ghqd_oNGPpHJUiqxaNXBzfRUBI_jgkrO5dFyVSdt7aDDxOJo4NiRTcFZLiCvvDTVkE4YWtF24wDDtLByN76bHgGvUBv8ZOofxo-fxDdR07JLUKlA8ARnayDXj7gP6ZUeaAq_cNiez6S1Ev1kYpfPtCaQl8RIDaNG0sQPd_L0dgcfE-iw_0aoX-fBf_lqnFhrCyKydBGChHREknQwxrPFuZVXsQV2PaigGoiqKQb6N1YZxmw97MOFRPm5TfKddYUL2AerpBBjnOrFAb4ZtDYJIBKPr6Tm8_9bv2e6CTabDl3iQ_ZyMZ_VFHqKce3aQnZ6_wfsH2a-P-nOvFv3POJ4BPnXGrw</recordid><startdate>20170327</startdate><enddate>20170327</enddate><creator>Peng, Qingpo</creator><creator>Li, Shujun</creator><creator>Wang, Ruoya</creator><creator>Liu, Shuxia</creator><creator>Xie, Linhua</creator><creator>Zhai, Jianxin</creator><creator>Zhang, Jie</creator><creator>Zhao, Qianyi</creator><creator>Chen, Xuenian</creator><scope/></search><sort><creationdate>20170327</creationdate><title>Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materialsElectronic supplementary information (ESI) available: Experimental procedures, crystallographic structures, FTIR spectroscopy, thermal analyses, PXRD patterns, and proton conductivity measurement for the title compounds. CCDC 1507115-1507117 and 1507119. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt00091j</title><author>Peng, Qingpo ; Li, Shujun ; Wang, Ruoya ; Liu, Shuxia ; Xie, Linhua ; Zhai, Jianxin ; Zhang, Jie ; Zhao, Qianyi ; Chen, Xuenian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7dt00091j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peng, Qingpo</creatorcontrib><creatorcontrib>Li, Shujun</creatorcontrib><creatorcontrib>Wang, Ruoya</creatorcontrib><creatorcontrib>Liu, Shuxia</creatorcontrib><creatorcontrib>Xie, Linhua</creatorcontrib><creatorcontrib>Zhai, Jianxin</creatorcontrib><creatorcontrib>Zhang, Jie</creatorcontrib><creatorcontrib>Zhao, Qianyi</creatorcontrib><creatorcontrib>Chen, Xuenian</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peng, Qingpo</au><au>Li, Shujun</au><au>Wang, Ruoya</au><au>Liu, Shuxia</au><au>Xie, Linhua</au><au>Zhai, Jianxin</au><au>Zhang, Jie</au><au>Zhao, Qianyi</au><au>Chen, Xuenian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materialsElectronic supplementary information (ESI) available: Experimental procedures, crystallographic structures, FTIR spectroscopy, thermal analyses, PXRD patterns, and proton conductivity measurement for the title compounds. CCDC 1507115-1507117 and 1507119. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt00091j</atitle><date>2017-03-27</date><risdate>2017</risdate><volume>46</volume><issue>13</issue><spage>4157</spage><epage>416</epage><pages>4157-416</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Four lanthanide derivatives of Ta-containing POMs [Ln
3
(H
2
O)
22
][P
2
W
15
Ta
3
O
62
]·
n
H
2
O (Ln = La,
1
; Ce,
2
; Pr,
3
; and Nd,
4
) were isolated by the self-assembly of Wells-Dawson type Ta/W mixed-addendum POM and lanthanide ions. Compound
1
showed excellent proton conduction performance at high relative humidities (RHs), with conductivity reaching 1.26 × 10
−2
S cm
−1
at 95 °C under 98% RH.
Four lanthanide derivatives were isolated by the self-assembly of {P
2
W
15
Ta
3
O
62
} and lanthanide ions, which showed good proton conduction performance.</abstract><doi>10.1039/c7dt00091j</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
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| language | eng |
| recordid | cdi_rsc_primary_c7dt00091j |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Lanthanide derivatives of Ta/W mixed-addendum POMs as proton-conducting materialsElectronic supplementary information (ESI) available: Experimental procedures, crystallographic structures, FTIR spectroscopy, thermal analyses, PXRD patterns, and proton conductivity measurement for the title compounds. CCDC 1507115-1507117 and 1507119. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt00091j |
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