Visible-light-induced photocatalytic benzene/cyclohexane cross-coupling utilizing a ligand-to-metal charge transfer benzene complex adsorbed on titanium oxides
The cross-coupling reaction of benzene and cyclohexane molecules proceeded selectively over Pd-modified titanium dioxide photocatalysts under visible light. A ligand-to-metal charge-transfer (LMCT) complex of benzene adsorbed on titanium oxide was proposed as the key species for the selective format...
Gespeichert in:
| Veröffentlicht in: | Catalysis science & technology 2018, Vol.8 (8), p.246-25 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 25 |
|---|---|
| container_issue | 8 |
| container_start_page | 246 |
| container_title | Catalysis science & technology |
| container_volume | 8 |
| creator | Yamamoto, A Ohara, T Yoshida, H |
| description | The cross-coupling reaction of benzene and cyclohexane molecules proceeded selectively over Pd-modified titanium dioxide photocatalysts under visible light. A ligand-to-metal charge-transfer (LMCT) complex of benzene adsorbed on titanium oxide was proposed as the key species for the selective formation of the cross-coupling product.
High selectivity was achieved in the photocatalytic cross-coupling of benzene and cyclohexane by photoexcitation of a surface benzene complex. |
| doi_str_mv | 10.1039/c7cy02566a |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_c7cy02566a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2030552257</sourcerecordid><originalsourceid>FETCH-LOGICAL-c384t-2c56e8de9e40eda1c8a2b4b12aad5e56cd57da37c52abde41e33c29c6cf7d8d43</originalsourceid><addsrcrecordid>eNpFkU1L5EAQhoOsoKgX70KDN6G10x9J5iiDuysIXlTwFCrVNTMtme5sdwdm_DP-VaPjal2qDg_PS_EWxWkpLkuhZldY41ZIU1WwVxxKoTXXdVX--r6NOihOUnoR0-hZKRp5WLw9ueS6nnjvlqvMnbcjkmXDKuSAkKHfZoesI_9Knq5wi31Y0QY8MYwhJY5hHHrnl2zMrnevHxewyQXe8hz4miYFwxXEJbEcwacFxf86hmE99LRhYFOI3RQbPMsug3fjmoWNs5SOi_0F9IlOvvZR8fj75mH-l9_d_7mdX99xVI3OXKKpqLE0Iy3IQokNyE53pQSwhkyF1tQWVI1GQmdJl6QUyhlWuKhtY7U6Ks533iGGfyOl3L6EMfopspVCCWOkNPVEXeyoz-cjLdohujXEbVuK9qODdl7Pnz87uJ7gsx0cE35zPx2pd3wMiSQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2030552257</pqid></control><display><type>article</type><title>Visible-light-induced photocatalytic benzene/cyclohexane cross-coupling utilizing a ligand-to-metal charge transfer benzene complex adsorbed on titanium oxides</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Yamamoto, A ; Ohara, T ; Yoshida, H</creator><creatorcontrib>Yamamoto, A ; Ohara, T ; Yoshida, H</creatorcontrib><description>The cross-coupling reaction of benzene and cyclohexane molecules proceeded selectively over Pd-modified titanium dioxide photocatalysts under visible light. A ligand-to-metal charge-transfer (LMCT) complex of benzene adsorbed on titanium oxide was proposed as the key species for the selective formation of the cross-coupling product.
High selectivity was achieved in the photocatalytic cross-coupling of benzene and cyclohexane by photoexcitation of a surface benzene complex.</description><identifier>ISSN: 2044-4753</identifier><identifier>EISSN: 2044-4761</identifier><identifier>DOI: 10.1039/c7cy02566a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Benzene ; Charge transfer ; Chemical industry ; Chemical reactions ; Coordination compounds ; Coupling (molecular) ; Cross coupling ; Cyclohexane ; Hydrocarbons ; Ligands ; Palladium ; Photocatalysis ; Titanium ; Titanium dioxide ; Titanium oxides</subject><ispartof>Catalysis science & technology, 2018, Vol.8 (8), p.246-25</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c384t-2c56e8de9e40eda1c8a2b4b12aad5e56cd57da37c52abde41e33c29c6cf7d8d43</citedby><cites>FETCH-LOGICAL-c384t-2c56e8de9e40eda1c8a2b4b12aad5e56cd57da37c52abde41e33c29c6cf7d8d43</cites><orcidid>0000-0002-1329-0807 ; 0000-0002-2540-0225</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,4012,27906,27907,27908</link.rule.ids></links><search><creatorcontrib>Yamamoto, A</creatorcontrib><creatorcontrib>Ohara, T</creatorcontrib><creatorcontrib>Yoshida, H</creatorcontrib><title>Visible-light-induced photocatalytic benzene/cyclohexane cross-coupling utilizing a ligand-to-metal charge transfer benzene complex adsorbed on titanium oxides</title><title>Catalysis science & technology</title><description>The cross-coupling reaction of benzene and cyclohexane molecules proceeded selectively over Pd-modified titanium dioxide photocatalysts under visible light. A ligand-to-metal charge-transfer (LMCT) complex of benzene adsorbed on titanium oxide was proposed as the key species for the selective formation of the cross-coupling product.
High selectivity was achieved in the photocatalytic cross-coupling of benzene and cyclohexane by photoexcitation of a surface benzene complex.</description><subject>Benzene</subject><subject>Charge transfer</subject><subject>Chemical industry</subject><subject>Chemical reactions</subject><subject>Coordination compounds</subject><subject>Coupling (molecular)</subject><subject>Cross coupling</subject><subject>Cyclohexane</subject><subject>Hydrocarbons</subject><subject>Ligands</subject><subject>Palladium</subject><subject>Photocatalysis</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><subject>Titanium oxides</subject><issn>2044-4753</issn><issn>2044-4761</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpFkU1L5EAQhoOsoKgX70KDN6G10x9J5iiDuysIXlTwFCrVNTMtme5sdwdm_DP-VaPjal2qDg_PS_EWxWkpLkuhZldY41ZIU1WwVxxKoTXXdVX--r6NOihOUnoR0-hZKRp5WLw9ueS6nnjvlqvMnbcjkmXDKuSAkKHfZoesI_9Knq5wi31Y0QY8MYwhJY5hHHrnl2zMrnevHxewyQXe8hz4miYFwxXEJbEcwacFxf86hmE99LRhYFOI3RQbPMsug3fjmoWNs5SOi_0F9IlOvvZR8fj75mH-l9_d_7mdX99xVI3OXKKpqLE0Iy3IQokNyE53pQSwhkyF1tQWVI1GQmdJl6QUyhlWuKhtY7U6Ks533iGGfyOl3L6EMfopspVCCWOkNPVEXeyoz-cjLdohujXEbVuK9qODdl7Pnz87uJ7gsx0cE35zPx2pd3wMiSQ</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Yamamoto, A</creator><creator>Ohara, T</creator><creator>Yoshida, H</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-1329-0807</orcidid><orcidid>https://orcid.org/0000-0002-2540-0225</orcidid></search><sort><creationdate>2018</creationdate><title>Visible-light-induced photocatalytic benzene/cyclohexane cross-coupling utilizing a ligand-to-metal charge transfer benzene complex adsorbed on titanium oxides</title><author>Yamamoto, A ; Ohara, T ; Yoshida, H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c384t-2c56e8de9e40eda1c8a2b4b12aad5e56cd57da37c52abde41e33c29c6cf7d8d43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Benzene</topic><topic>Charge transfer</topic><topic>Chemical industry</topic><topic>Chemical reactions</topic><topic>Coordination compounds</topic><topic>Coupling (molecular)</topic><topic>Cross coupling</topic><topic>Cyclohexane</topic><topic>Hydrocarbons</topic><topic>Ligands</topic><topic>Palladium</topic><topic>Photocatalysis</topic><topic>Titanium</topic><topic>Titanium dioxide</topic><topic>Titanium oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yamamoto, A</creatorcontrib><creatorcontrib>Ohara, T</creatorcontrib><creatorcontrib>Yoshida, H</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Catalysis science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yamamoto, A</au><au>Ohara, T</au><au>Yoshida, H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Visible-light-induced photocatalytic benzene/cyclohexane cross-coupling utilizing a ligand-to-metal charge transfer benzene complex adsorbed on titanium oxides</atitle><jtitle>Catalysis science & technology</jtitle><date>2018</date><risdate>2018</risdate><volume>8</volume><issue>8</issue><spage>246</spage><epage>25</epage><pages>246-25</pages><issn>2044-4753</issn><eissn>2044-4761</eissn><abstract>The cross-coupling reaction of benzene and cyclohexane molecules proceeded selectively over Pd-modified titanium dioxide photocatalysts under visible light. A ligand-to-metal charge-transfer (LMCT) complex of benzene adsorbed on titanium oxide was proposed as the key species for the selective formation of the cross-coupling product.
High selectivity was achieved in the photocatalytic cross-coupling of benzene and cyclohexane by photoexcitation of a surface benzene complex.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c7cy02566a</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-1329-0807</orcidid><orcidid>https://orcid.org/0000-0002-2540-0225</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2044-4753 |
| ispartof | Catalysis science & technology, 2018, Vol.8 (8), p.246-25 |
| issn | 2044-4753 2044-4761 |
| language | eng |
| recordid | cdi_rsc_primary_c7cy02566a |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Benzene Charge transfer Chemical industry Chemical reactions Coordination compounds Coupling (molecular) Cross coupling Cyclohexane Hydrocarbons Ligands Palladium Photocatalysis Titanium Titanium dioxide Titanium oxides |
| title | Visible-light-induced photocatalytic benzene/cyclohexane cross-coupling utilizing a ligand-to-metal charge transfer benzene complex adsorbed on titanium oxides |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T10%3A30%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Visible-light-induced%20photocatalytic%20benzene/cyclohexane%20cross-coupling%20utilizing%20a%20ligand-to-metal%20charge%20transfer%20benzene%20complex%20adsorbed%20on%20titanium%20oxides&rft.jtitle=Catalysis%20science%20&%20technology&rft.au=Yamamoto,%20A&rft.date=2018&rft.volume=8&rft.issue=8&rft.spage=246&rft.epage=25&rft.pages=246-25&rft.issn=2044-4753&rft.eissn=2044-4761&rft_id=info:doi/10.1039/c7cy02566a&rft_dat=%3Cproquest_rsc_p%3E2030552257%3C/proquest_rsc_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2030552257&rft_id=info:pmid/&rfr_iscdi=true |