Sensing the framework state and guest molecules in MIL-53(Al) via the electron paramagnetic resonance spectrum of VIV dopant ionsElectronic supplementary information (ESI) available: X-Ray powder diffraction patterns and N2 adsorption isotherms of reported samples, available lattice parameters for three states in MIL-53(Al) and MIL-53(Ga), hydration of np-d followed in situ with EPR spectroscopy, simulation of activated V-doped MIL-53(Al) in np-h state with two components, superhyperfine interac

X-ray diffraction (XRD) and electron paramagnetic resonance spectroscopy (EPR) were combined to study the structural transformations induced by temperature, pressure and air humidity of the "breathing" metal-organic framework (MOF) MIL-53(Al), doped with paramagnetic V IV ions, after activ...

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Hauptverfasser: Nevjesti, Irena, Depauw, Hannes, Gast, Peter, Tack, Pieter, Deduytsche, Davy, Leus, Karen, Van Landeghem, Melissa, Goovaerts, Etienne, Vincze, Laszlo, Detavernier, Christophe, Van Der Voort, Pascal, Callens, Freddy, Vrielinck, Henk
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Sprache:eng
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