Accurate experimental and theoretical enthalpies of association of TiCl4 with typical Lewis bases used in heterogeneous Ziegler-Natta catalysisElectronic supplementary information (ESI) available: Calorimetry details, Cartesian coordinates, and energies. See DOI: 10.1039/c7cp04047d
Adducts of TiCl 4 with Lewis bases used as internal or external donors in heterogeneous Ziegler-Natta (ZN) catalysis represent a fundamental interaction contributing to the final composition of MgCl 2 supported ZN-catalysts. This study presents the accurate experimental evaluation, from titration ca...
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