Solution of an elusive pigment crystal structure from a thin film: a combined X-ray diffraction and computational studyElectronic supplementary information (ESI) available: AFM micrographs of ∼7 nm thick samples; XRR data of ∼7 nm thick samples prepared at substrate temperatures of 200 and 350 K, including data fits and electron density profiles; chemical structure diagrams of the 2F-EPI and 2Cl-EPI derivatives; overlays of the thin film EPI structure with the halogenated derivative structures;
Epindolidione, a hydrogen-bonded derivative of the organic semiconductor tetracene, is an organic pigment which has previously been used to produce stable OFETs with relatively high hole mobilities. Despite its use as an inkjet pigment and organic semiconductor, the crystal structure of epindolidion...
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