Hexacyano-[3]-radialene anion-radical salts: a promising family of highly soluble p-dopantsElectronic supplementary information (ESI) available: Synthesis of the dopants, cyclic voltammetry, thermal, X-ray, and microscopy data. See DOI: 10.1039/c7cc08671g
Organic and inorganic salts of the hexacyano-[3]-radialene anion-radical are readily available and thermally stable compounds (up to ∼180 °C). The tetrabutylammonium salt exhibits an extremely high solubility in a range of solvents (>300 mg l −1 in CHCl 3 ) and acts as an efficient p-dopant for p...
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| creator | Karpov, Y Kiriy, N Al-Hussein, M Hambsch, M Beryozkina, T Bakulev, V Mannsfeld, S. C. B Voit, B Kiriy, A |
| description | Organic and inorganic salts of the hexacyano-[3]-radialene anion-radical are readily available and thermally stable compounds (up to ∼180 °C). The tetrabutylammonium salt exhibits an extremely high solubility in a range of solvents (>300 mg l
−1
in CHCl
3
) and acts as an efficient p-dopant for poly(3-hexylthiophene) to provide composite films with a conductivity above 2 S cm
−1
.
A versatile approach to a family of thermally stable, efficient anion-radical p-dopants having a tunable solubility is developed. |
| doi_str_mv | 10.1039/c7cc08671g |
| format | Article |
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−1
in CHCl
3
) and acts as an efficient p-dopant for poly(3-hexylthiophene) to provide composite films with a conductivity above 2 S cm
−1
.
A versatile approach to a family of thermally stable, efficient anion-radical p-dopants having a tunable solubility is developed.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c7cc08671g</identifier><language>eng</language><creationdate>2018-01</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Karpov, Y</creatorcontrib><creatorcontrib>Kiriy, N</creatorcontrib><creatorcontrib>Al-Hussein, M</creatorcontrib><creatorcontrib>Hambsch, M</creatorcontrib><creatorcontrib>Beryozkina, T</creatorcontrib><creatorcontrib>Bakulev, V</creatorcontrib><creatorcontrib>Mannsfeld, S. C. B</creatorcontrib><creatorcontrib>Voit, B</creatorcontrib><creatorcontrib>Kiriy, A</creatorcontrib><title>Hexacyano-[3]-radialene anion-radical salts: a promising family of highly soluble p-dopantsElectronic supplementary information (ESI) available: Synthesis of the dopants, cyclic voltammetry, thermal, X-ray, and microscopy data. See DOI: 10.1039/c7cc08671g</title><description>Organic and inorganic salts of the hexacyano-[3]-radialene anion-radical are readily available and thermally stable compounds (up to ∼180 °C). The tetrabutylammonium salt exhibits an extremely high solubility in a range of solvents (>300 mg l
−1
in CHCl
3
) and acts as an efficient p-dopant for poly(3-hexylthiophene) to provide composite films with a conductivity above 2 S cm
−1
.
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−1
in CHCl
3
) and acts as an efficient p-dopant for poly(3-hexylthiophene) to provide composite films with a conductivity above 2 S cm
−1
.
A versatile approach to a family of thermally stable, efficient anion-radical p-dopants having a tunable solubility is developed.</abstract><doi>10.1039/c7cc08671g</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Hexacyano-[3]-radialene anion-radical salts: a promising family of highly soluble p-dopantsElectronic supplementary information (ESI) available: Synthesis of the dopants, cyclic voltammetry, thermal, X-ray, and microscopy data. See DOI: 10.1039/c7cc08671g |
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