A novel red-emitting K2Ca(PO4)F:Eu2+ phosphor with a large Stokes shiftElectronic supplementary information (ESI) available: Configuration states, CPMAS spectra using solid state NMR, PL spectra dependence on the temperature, PLE spectra using pc-LEDs, crystallographic data, atomic coordinates, bond distance and angles, phase transition data, result of CDFT calculations, pc-LEDs performance. See DOI: 10.1039/c7cc08202a
We report a K 2 CaPO 4 F:Eu 2+ phosphor with a new crystal structure. This phosphor has a large Stokes shift and converts near-ultraviolet light to red luminescence without absorption of other visible light. The mechanism was elucidated by applying a constrained density functional theory to the solv...
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| creator | Daicho, H Shinomiya, Y Enomoto, K Nakano, A Sawa, H Matsuishi, S Hosono, H |
| description | We report a K
2
CaPO
4
F:Eu
2+
phosphor with a new crystal structure. This phosphor has a large Stokes shift and converts near-ultraviolet light to red luminescence without absorption of other visible light. The mechanism was elucidated by applying a constrained density functional theory to the solved crystal structure.
We report a K
2
CaPO
4
F:Eu
2+
phosphor with a new crystal structure. |
| doi_str_mv | 10.1039/c7cc08202a |
| format | Article |
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2
CaPO
4
F:Eu
2+
phosphor with a new crystal structure. This phosphor has a large Stokes shift and converts near-ultraviolet light to red luminescence without absorption of other visible light. The mechanism was elucidated by applying a constrained density functional theory to the solved crystal structure.
We report a K
2
CaPO
4
F:Eu
2+
phosphor with a new crystal structure.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c7cc08202a</identifier><language>eng</language><creationdate>2018-01</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Daicho, H</creatorcontrib><creatorcontrib>Shinomiya, Y</creatorcontrib><creatorcontrib>Enomoto, K</creatorcontrib><creatorcontrib>Nakano, A</creatorcontrib><creatorcontrib>Sawa, H</creatorcontrib><creatorcontrib>Matsuishi, S</creatorcontrib><creatorcontrib>Hosono, H</creatorcontrib><title>A novel red-emitting K2Ca(PO4)F:Eu2+ phosphor with a large Stokes shiftElectronic supplementary information (ESI) available: Configuration states, CPMAS spectra using solid state NMR, PL spectra dependence on the temperature, PLE spectra using pc-LEDs, crystallographic data, atomic coordinates, bond distance and angles, phase transition data, result of CDFT calculations, pc-LEDs performance. See DOI: 10.1039/c7cc08202a</title><description>We report a K
2
CaPO
4
F:Eu
2+
phosphor with a new crystal structure. This phosphor has a large Stokes shift and converts near-ultraviolet light to red luminescence without absorption of other visible light. The mechanism was elucidated by applying a constrained density functional theory to the solved crystal structure.
We report a K
2
CaPO
4
F:Eu
2+
phosphor with a new crystal structure.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFUU1P4zAQzSKQlgUu3JGGG4iGTZt2Kb2hNBWIr2rLgVs12JPEu45t2Q4r_hC_E6dBiwQSWLLs0Xt-7804inb7yXE_SU9_shPGkvEgGeBatNlPfw3j0XB8v97eR6fxSTocfY9-OPcnCas_Gm9-ez4DpR9JgiUeUy28F6qEy0GGB_Pb4eFskjeDIzCVdmFb-Cd8BQgSbUmw8PovOXCVKHwuiXmrlWDgGmMk1aQ82icQqtC2Ri-0goN8cXEI-IhC4oOkCWRaFaJsbAc7j55cD7L59dkCnGkVERrXJnJaCt4x4Ob6dw_mV_8ZnAwpTooRBBVfEXiqDQXVxlLLzN-JGRZf5dPgxOxTkJRSlxZNFbJz9NgD9LoOBdPacqG6UA9aceAi0FsfDAWqUraIqdAFS4vKiVUfnYgl10gPuoBsOrsDhpI1ctVo-6ZLACHlajxB8xgWRDC9vZjAx9_cjjYKlI52Xs-taG-W32XnsXVsaayow6iXb_T0a3z_M3xpeJG-AMU1woU</recordid><startdate>20180123</startdate><enddate>20180123</enddate><creator>Daicho, H</creator><creator>Shinomiya, Y</creator><creator>Enomoto, K</creator><creator>Nakano, A</creator><creator>Sawa, H</creator><creator>Matsuishi, S</creator><creator>Hosono, H</creator><scope/></search><sort><creationdate>20180123</creationdate><title>A novel red-emitting K2Ca(PO4)F:Eu2+ phosphor with a large Stokes shiftElectronic supplementary information (ESI) available: Configuration states, CPMAS spectra using solid state NMR, PL spectra dependence on the temperature, PLE spectra using pc-LEDs, crystallographic data, atomic coordinates, bond distance and angles, phase transition data, result of CDFT calculations, pc-LEDs performance. See DOI: 10.1039/c7cc08202a</title><author>Daicho, H ; Shinomiya, Y ; Enomoto, K ; Nakano, A ; Sawa, H ; Matsuishi, S ; Hosono, H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c7cc08202a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Daicho, H</creatorcontrib><creatorcontrib>Shinomiya, Y</creatorcontrib><creatorcontrib>Enomoto, K</creatorcontrib><creatorcontrib>Nakano, A</creatorcontrib><creatorcontrib>Sawa, H</creatorcontrib><creatorcontrib>Matsuishi, S</creatorcontrib><creatorcontrib>Hosono, H</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Daicho, H</au><au>Shinomiya, Y</au><au>Enomoto, K</au><au>Nakano, A</au><au>Sawa, H</au><au>Matsuishi, S</au><au>Hosono, H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel red-emitting K2Ca(PO4)F:Eu2+ phosphor with a large Stokes shiftElectronic supplementary information (ESI) available: Configuration states, CPMAS spectra using solid state NMR, PL spectra dependence on the temperature, PLE spectra using pc-LEDs, crystallographic data, atomic coordinates, bond distance and angles, phase transition data, result of CDFT calculations, pc-LEDs performance. See DOI: 10.1039/c7cc08202a</atitle><date>2018-01-23</date><risdate>2018</risdate><volume>54</volume><issue>8</issue><spage>884</spage><epage>887</epage><pages>884-887</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We report a K
2
CaPO
4
F:Eu
2+
phosphor with a new crystal structure. This phosphor has a large Stokes shift and converts near-ultraviolet light to red luminescence without absorption of other visible light. The mechanism was elucidated by applying a constrained density functional theory to the solved crystal structure.
We report a K
2
CaPO
4
F:Eu
2+
phosphor with a new crystal structure.</abstract><doi>10.1039/c7cc08202a</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | A novel red-emitting K2Ca(PO4)F:Eu2+ phosphor with a large Stokes shiftElectronic supplementary information (ESI) available: Configuration states, CPMAS spectra using solid state NMR, PL spectra dependence on the temperature, PLE spectra using pc-LEDs, crystallographic data, atomic coordinates, bond distance and angles, phase transition data, result of CDFT calculations, pc-LEDs performance. See DOI: 10.1039/c7cc08202a |
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