Spectroscopic characterization of (diiodomethyl)zinc iodide: application to the stereoselective synthesis and functionalization of iodocyclopropanesElectronic supplementary information (ESI) available. CCDC 1554344. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc04348a
Herein is described an improved synthetic route to enantio- and diastereoenriched iodocyclopropylmethanols using (diiodomethyl)zinc iodide etherate as the active species. The products obtained by this methodology were successfully functionalized by Suzuki-Miyaura cross-coupling reactions. A Buchwald...
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