Amino acid functionalisation using the 2-phosphaethynolate anion. A facile route to (phosphanyl)carbonyl-amino acidsElectronic supplementary information (ESI) available: Full experimental details including spectra and computational data. CCDC 1533100. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc01285c

Amino acid functionalisation using the 2-phosphaethynolate anion. A facile route to (phosphanyl)carbonyl-amino acidsElectronic supplementary information (ESI) available: Full experimental details including spectra and computational data. CCDC 1533100. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc01285c

We describe the reactivity of the 2-phosphaethynolate anion (PCO − ) towards enantiomerically pure α-amino acids (AAs) resulting in the formation of novel salts of phosphinecarboxamides bearing chiral functionalities. These transformations occurred quantitatively with all but one of the amino acids...

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Hauptverfasser: Faria, E. N, Jupp, A. R, Goicoechea, J. M
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Sprache:eng
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