Generating new magnetic properties in organic-inorganic hybridsElectronic supplementary information (ESI) available. See DOI: 10.1039/c6tc04737h

Organic-inorganic hybrids are a rapidly developing class of multifunctional materials, which can present properties different from those of either of their building blocks. Control over the structure during the assembly process is crucial to achieve the desired functions. Here we present the layer-by-layer deposition in ambient conditions of CoCl 4 -octahedra or MnCl 4 -octahedra and organic layers to tailor their magnetic properties. The Langmuir-Blodgett technique used to assemble these structures provides intrinsic control over the film structure down to the molecular level. Magnetic characterization reveals that MnCl 4 -based hybrid Langmuir-Blodgett films order antiferromagnetically like the bulk hybrid, while the CoCl 4 -based hybrid Langmuir-Blodgett films show ferromagnetic coupling in contrast to the bulk hybrid, which is a paramagnet. Organic-inorganic hybrids are a rapidly developing class of multifunctional materials, which can present properties different from those of either of their building blocks.