as a low-cost 'Spiro' hole-transport material for efficient perovskite solar cells
Four spiro[fluorene-9,9′-xanthene] ( SFX ) derivatives, SFX-TAD , SFX-TCz , SFX-TPTZ and SFX-MeOTAD have been synthesized for use as hole-transport materials and fully characterized by 1 H/ 13 C NMR spectroscopy, mass spectrometry, XRD and DSC. Their thermal, optical and electrochemical properties w...
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| Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2016-03, Vol.4 (13), p.4855-4863 |
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| container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
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| creator | Maciejczyk, Michal Ivaturi, Aruna Robertson, Neil |
| description | Four spiro[fluorene-9,9′-xanthene] (
SFX
) derivatives,
SFX-TAD
,
SFX-TCz
,
SFX-TPTZ
and
SFX-MeOTAD
have been synthesized for use as hole-transport materials and fully characterized by
1
H/
13
C NMR spectroscopy, mass spectrometry, XRD and DSC. Their thermal, optical and electrochemical properties were investigated. The use of different substituents affects the highest occupied molecular orbital (HOMO) energy level proving the versatility of the central core towards the facile and low-cost preparation of spiro-hole-transport materials. Among the synthesized
SFX
derivatives,
SFX-MeOTAD
was employed as hole-transporting material (HTM) and the performance tested in perovskite solar cells with device architecture glass/FTO/compact TiO
2
/mesoporous Al
2
O
3
/CH
3
NH
3
PbI
3−
x
Cl
x
/HTM/Au.
SFX-MeOTAD
gave a comparable efficiency to
spiro-MeOTAD
, demonstrating great potential for use of the
SFX
family as cost effective and versatile hole conductors facilitating commercialization of perovskite solar cells (PSCs).
Four spiro[fluorene-9,9′-xanthene] (
SFX
) derivatives,
SFX-TAD
,
SFX-TCz
,
SFX-TPTZ
and
SFX-MeOTAD
have been synthesized for use as hole-transport materials and fully characterized by
1
H/
13
C NMR spectroscopy, mass spectrometry, XRD and DSC. |
| doi_str_mv | 10.1039/c6ta00110f |
| format | Article |
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SFX
) derivatives,
SFX-TAD
,
SFX-TCz
,
SFX-TPTZ
and
SFX-MeOTAD
have been synthesized for use as hole-transport materials and fully characterized by
1
H/
13
C NMR spectroscopy, mass spectrometry, XRD and DSC. Their thermal, optical and electrochemical properties were investigated. The use of different substituents affects the highest occupied molecular orbital (HOMO) energy level proving the versatility of the central core towards the facile and low-cost preparation of spiro-hole-transport materials. Among the synthesized
SFX
derivatives,
SFX-MeOTAD
was employed as hole-transporting material (HTM) and the performance tested in perovskite solar cells with device architecture glass/FTO/compact TiO
2
/mesoporous Al
2
O
3
/CH
3
NH
3
PbI
3−
x
Cl
x
/HTM/Au.
SFX-MeOTAD
gave a comparable efficiency to
spiro-MeOTAD
, demonstrating great potential for use of the
SFX
family as cost effective and versatile hole conductors facilitating commercialization of perovskite solar cells (PSCs).
Four spiro[fluorene-9,9′-xanthene] (
SFX
) derivatives,
SFX-TAD
,
SFX-TCz
,
SFX-TPTZ
and
SFX-MeOTAD
have been synthesized for use as hole-transport materials and fully characterized by
1
H/
13
C NMR spectroscopy, mass spectrometry, XRD and DSC.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/c6ta00110f</identifier><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2016-03, Vol.4 (13), p.4855-4863</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Maciejczyk, Michal</creatorcontrib><creatorcontrib>Ivaturi, Aruna</creatorcontrib><creatorcontrib>Robertson, Neil</creatorcontrib><title>as a low-cost 'Spiro' hole-transport material for efficient perovskite solar cells</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>Four spiro[fluorene-9,9′-xanthene] (
SFX
) derivatives,
SFX-TAD
,
SFX-TCz
,
SFX-TPTZ
and
SFX-MeOTAD
have been synthesized for use as hole-transport materials and fully characterized by
1
H/
13
C NMR spectroscopy, mass spectrometry, XRD and DSC. Their thermal, optical and electrochemical properties were investigated. The use of different substituents affects the highest occupied molecular orbital (HOMO) energy level proving the versatility of the central core towards the facile and low-cost preparation of spiro-hole-transport materials. Among the synthesized
SFX
derivatives,
SFX-MeOTAD
was employed as hole-transporting material (HTM) and the performance tested in perovskite solar cells with device architecture glass/FTO/compact TiO
2
/mesoporous Al
2
O
3
/CH
3
NH
3
PbI
3−
x
Cl
x
/HTM/Au.
SFX-MeOTAD
gave a comparable efficiency to
spiro-MeOTAD
, demonstrating great potential for use of the
SFX
family as cost effective and versatile hole conductors facilitating commercialization of perovskite solar cells (PSCs).
Four spiro[fluorene-9,9′-xanthene] (
SFX
) derivatives,
SFX-TAD
,
SFX-TCz
,
SFX-TPTZ
and
SFX-MeOTAD
have been synthesized for use as hole-transport materials and fully characterized by
1
H/
13
C NMR spectroscopy, mass spectrometry, XRD and DSC.</description><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjj0LAjEQBYMoKHqNvbCd1enGj_OuFsVa7Y8lJBiN5tgNiv9eC9HS18zANE-pocaJxnk1NUUiRK3RtVRvhkvMV4uqaH-9LLsqEznjeyViUVU9tScBghAfuYmSYHxoPMcxnGKweWK6SRM5wZWSZU8BXGSwznnj7S1BYzne5eKTBYmBGIwNQQaq4yiIzT7sq9F2c1zvchZTN-yvxM_693X-r78A81VCIw</recordid><startdate>20160322</startdate><enddate>20160322</enddate><creator>Maciejczyk, Michal</creator><creator>Ivaturi, Aruna</creator><creator>Robertson, Neil</creator><scope/></search><sort><creationdate>20160322</creationdate><title>as a low-cost 'Spiro' hole-transport material for efficient perovskite solar cells</title><author>Maciejczyk, Michal ; Ivaturi, Aruna ; Robertson, Neil</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c6ta00110f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maciejczyk, Michal</creatorcontrib><creatorcontrib>Ivaturi, Aruna</creatorcontrib><creatorcontrib>Robertson, Neil</creatorcontrib><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maciejczyk, Michal</au><au>Ivaturi, Aruna</au><au>Robertson, Neil</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>as a low-cost 'Spiro' hole-transport material for efficient perovskite solar cells</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2016-03-22</date><risdate>2016</risdate><volume>4</volume><issue>13</issue><spage>4855</spage><epage>4863</epage><pages>4855-4863</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>Four spiro[fluorene-9,9′-xanthene] (
SFX
) derivatives,
SFX-TAD
,
SFX-TCz
,
SFX-TPTZ
and
SFX-MeOTAD
have been synthesized for use as hole-transport materials and fully characterized by
1
H/
13
C NMR spectroscopy, mass spectrometry, XRD and DSC. Their thermal, optical and electrochemical properties were investigated. The use of different substituents affects the highest occupied molecular orbital (HOMO) energy level proving the versatility of the central core towards the facile and low-cost preparation of spiro-hole-transport materials. Among the synthesized
SFX
derivatives,
SFX-MeOTAD
was employed as hole-transporting material (HTM) and the performance tested in perovskite solar cells with device architecture glass/FTO/compact TiO
2
/mesoporous Al
2
O
3
/CH
3
NH
3
PbI
3−
x
Cl
x
/HTM/Au.
SFX-MeOTAD
gave a comparable efficiency to
spiro-MeOTAD
, demonstrating great potential for use of the
SFX
family as cost effective and versatile hole conductors facilitating commercialization of perovskite solar cells (PSCs).
Four spiro[fluorene-9,9′-xanthene] (
SFX
) derivatives,
SFX-TAD
,
SFX-TCz
,
SFX-TPTZ
and
SFX-MeOTAD
have been synthesized for use as hole-transport materials and fully characterized by
1
H/
13
C NMR spectroscopy, mass spectrometry, XRD and DSC.</abstract><doi>10.1039/c6ta00110f</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7488 |
| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2016-03, Vol.4 (13), p.4855-4863 |
| issn | 2050-7488 2050-7496 |
| language | |
| recordid | cdi_rsc_primary_c6ta00110f |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | as a low-cost 'Spiro' hole-transport material for efficient perovskite solar cells |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-25T02%3A10%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=as%20a%20low-cost%20'Spiro'%20hole-transport%20material%20for%20efficient%20perovskite%20solar%20cells&rft.jtitle=Journal%20of%20materials%20chemistry.%20A,%20Materials%20for%20energy%20and%20sustainability&rft.au=Maciejczyk,%20Michal&rft.date=2016-03-22&rft.volume=4&rft.issue=13&rft.spage=4855&rft.epage=4863&rft.pages=4855-4863&rft.issn=2050-7488&rft.eissn=2050-7496&rft_id=info:doi/10.1039/c6ta00110f&rft_dat=%3Crsc%3Ec6ta00110f%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |