Conformations of cyclopentasilane stereoisomers control molecular junction conductance

Here we examine the impact of ring conformation on the charge transport characteristics of cyclic pentasilane structures bound to gold electrodes in single molecule junctions. We investigate the conductance properties of alkylated cyclopentasilane cis and trans stereoisomers substituted in the 1,3-p...

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Veröffentlicht in:	Chemical science (Cambridge) 2016-01, Vol.7 (9), p.5657-5662
Hauptverfasser:	Li, Haixing, Garner, Marc H, Shangguan, Zhichun, Zheng, Qianwen, Su, Timothy A, Neupane, Madhav, Li, Panpan, Velian, Alexandra, Steigerwald, Michael L, Xiao, Shengxiong, Nuckolls, Colin, Solomon, Gemma C, Venkataraman, Latha
Format:	Artikel
Sprache:	eng
Schlagworte:	Binding Conductance Constraints Electrodes Isomers Mathematical analysis Molecular structure Silanes
Online-Zugang:	Volltext
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