A fluorescent chemosensor for Sn and Cu based on a carbazole-containing diarylethene
A novel diarylethene with a carbazole moiety was developed for the highly selective and sensitive detection of Sn 2+ and Cu 2+ in methanol. Its fluorescence was enhanced with a 76 nm blue shift and selective fluorescence quenching occurred upon the addition of Sn 2+ and Cu 2+ , respectively, over a...
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Veröffentlicht in: | RSC advances 2017-02, Vol.7 (16), p.9833-9839 |
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creator | Qu, Shengzu Zheng, Chunhong Liao, Guanming Fan, Congbin Liu, Gang Pu, Shouzhi |
description | A novel diarylethene with a carbazole moiety was developed for the highly selective and sensitive detection of Sn
2+
and Cu
2+
in methanol. Its fluorescence was enhanced with a 76 nm blue shift and selective fluorescence quenching occurred upon the addition of Sn
2+
and Cu
2+
, respectively, over a wide range of tested cations. The compound formed complexes with Sn
2+
and Cu
2+
in a 1 : 1 stoichiometry and has the detection limits of 1.9 μM and 1.2 μM, respectively. Moreover, the compound can be applied to detect Sn
2+
and Cu
2+
in natural water samples with high accuracy.
A carbazole-containing diarylethene was synthesized. Its fluorescence was enhanced and quenched, respectively, upon addition of Sn
2+
and Cu
2+
over other cations. Moreover, the compound can be applied to detect Sn
2+
and Cu
2+
in natural water sample. |
doi_str_mv | 10.1039/c6ra27339d |
format | Article |
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2+
and Cu
2+
in methanol. Its fluorescence was enhanced with a 76 nm blue shift and selective fluorescence quenching occurred upon the addition of Sn
2+
and Cu
2+
, respectively, over a wide range of tested cations. The compound formed complexes with Sn
2+
and Cu
2+
in a 1 : 1 stoichiometry and has the detection limits of 1.9 μM and 1.2 μM, respectively. Moreover, the compound can be applied to detect Sn
2+
and Cu
2+
in natural water samples with high accuracy.
A carbazole-containing diarylethene was synthesized. Its fluorescence was enhanced and quenched, respectively, upon addition of Sn
2+
and Cu
2+
over other cations. Moreover, the compound can be applied to detect Sn
2+
and Cu
2+
in natural water sample.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c6ra27339d</identifier><language>eng</language><ispartof>RSC advances, 2017-02, Vol.7 (16), p.9833-9839</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,27924,27925</link.rule.ids></links><search><creatorcontrib>Qu, Shengzu</creatorcontrib><creatorcontrib>Zheng, Chunhong</creatorcontrib><creatorcontrib>Liao, Guanming</creatorcontrib><creatorcontrib>Fan, Congbin</creatorcontrib><creatorcontrib>Liu, Gang</creatorcontrib><creatorcontrib>Pu, Shouzhi</creatorcontrib><title>A fluorescent chemosensor for Sn and Cu based on a carbazole-containing diarylethene</title><title>RSC advances</title><description>A novel diarylethene with a carbazole moiety was developed for the highly selective and sensitive detection of Sn
2+
and Cu
2+
in methanol. Its fluorescence was enhanced with a 76 nm blue shift and selective fluorescence quenching occurred upon the addition of Sn
2+
and Cu
2+
, respectively, over a wide range of tested cations. The compound formed complexes with Sn
2+
and Cu
2+
in a 1 : 1 stoichiometry and has the detection limits of 1.9 μM and 1.2 μM, respectively. Moreover, the compound can be applied to detect Sn
2+
and Cu
2+
in natural water samples with high accuracy.
A carbazole-containing diarylethene was synthesized. Its fluorescence was enhanced and quenched, respectively, upon addition of Sn
2+
and Cu
2+
over other cations. Moreover, the compound can be applied to detect Sn
2+
and Cu
2+
in natural water sample.</description><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNp9T01LAzEUDIJgqb14F-IPWM1LdpPNsRS_oODBel6yLy92ZZuUZHvQX--CgjcHhmEYGGYYuwJxC0LZO9TZSaOU9WdsIUWtKym0vWCrUj7EDN2A1LBguzUP4yllKkhx4rinQyoUS8o8zHyN3EXPNyfeu0Kep9lzdLl3X2mkClOc3BCH-M794PLnSNOeIl2y8-DGQqtfXbK3h_vd5qnavjw-b9bbKgO0UxVMSyAtBdP7FhDAYF3b3irh0FsjfdA6OGhDsAp7T1SbxjRIQmmovfRqya5_enPB7piHwzyh-3s-5zf_5d3RB_UNDpZa1A</recordid><startdate>20170202</startdate><enddate>20170202</enddate><creator>Qu, Shengzu</creator><creator>Zheng, Chunhong</creator><creator>Liao, Guanming</creator><creator>Fan, Congbin</creator><creator>Liu, Gang</creator><creator>Pu, Shouzhi</creator><scope/></search><sort><creationdate>20170202</creationdate><title>A fluorescent chemosensor for Sn and Cu based on a carbazole-containing diarylethene</title><author>Qu, Shengzu ; Zheng, Chunhong ; Liao, Guanming ; Fan, Congbin ; Liu, Gang ; Pu, Shouzhi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-r118t-f78e129ef7bd81c117c449b930acd972df66fa18ff93cbdee47575ce03614d2d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qu, Shengzu</creatorcontrib><creatorcontrib>Zheng, Chunhong</creatorcontrib><creatorcontrib>Liao, Guanming</creatorcontrib><creatorcontrib>Fan, Congbin</creatorcontrib><creatorcontrib>Liu, Gang</creatorcontrib><creatorcontrib>Pu, Shouzhi</creatorcontrib><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qu, Shengzu</au><au>Zheng, Chunhong</au><au>Liao, Guanming</au><au>Fan, Congbin</au><au>Liu, Gang</au><au>Pu, Shouzhi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A fluorescent chemosensor for Sn and Cu based on a carbazole-containing diarylethene</atitle><jtitle>RSC advances</jtitle><date>2017-02-02</date><risdate>2017</risdate><volume>7</volume><issue>16</issue><spage>9833</spage><epage>9839</epage><pages>9833-9839</pages><eissn>2046-2069</eissn><abstract>A novel diarylethene with a carbazole moiety was developed for the highly selective and sensitive detection of Sn
2+
and Cu
2+
in methanol. Its fluorescence was enhanced with a 76 nm blue shift and selective fluorescence quenching occurred upon the addition of Sn
2+
and Cu
2+
, respectively, over a wide range of tested cations. The compound formed complexes with Sn
2+
and Cu
2+
in a 1 : 1 stoichiometry and has the detection limits of 1.9 μM and 1.2 μM, respectively. Moreover, the compound can be applied to detect Sn
2+
and Cu
2+
in natural water samples with high accuracy.
A carbazole-containing diarylethene was synthesized. Its fluorescence was enhanced and quenched, respectively, upon addition of Sn
2+
and Cu
2+
over other cations. Moreover, the compound can be applied to detect Sn
2+
and Cu
2+
in natural water sample.</abstract><doi>10.1039/c6ra27339d</doi><tpages>7</tpages></addata></record> |
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ispartof | RSC advances, 2017-02, Vol.7 (16), p.9833-9839 |
issn | 2046-2069 |
language | eng |
recordid | cdi_rsc_primary_c6ra27339d |
source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
title | A fluorescent chemosensor for Sn and Cu based on a carbazole-containing diarylethene |
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