p-Bromoaryl- and ω-bromoalkyl-VA-PNBs: suitable starting materials for the functionalization of vinylic addition polynorbornenes via palladium-catalyzed cross-coupling reactionsElectronic supplementary information (ESI) available: Additional tables with experimental data, and IR and solution or solid state NMR spectra of the polymers. See DOI: 10.1039/c6ra23123c
New vinylic addition polynorbornenes (VA-PNBs) with a variable amount of pendant 4-bromoaryl groups have been synthesized by homo- and copolymerization with norbornene of 2-(4-bromophenyl)-5-norbornene catalyzed by [Ni(C 6 F 5 ) 2 (SbPh 3 ) 2 ]. These polymers can be transformed by Pd-catalyzed cros...
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