Palladium-copper catalyzed C(sp)-C(sp) bond C-H activation cross-coupling reaction: selective arylation to synthesize 9-aryl-9-xanthene and 9,9-diaryl-xanthene derivatives

A novel cooperatively catalyzed C(sp 3 )-C(sp 2 ) bond C-H activation cross-coupling reaction has been developed. A series of 9-aryl-9 H -xanthenes and 9,9-diaryl-xanthenes were selectively synthesized in moderate to good yields by controlling the reaction time and temperature. A novel palladium-cop...

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Veröffentlicht in:RSC advances 2016-09, Vol.6 (88), p.84748-84751
Hauptverfasser: Shen, Guodong, Zhao, Lingyu, Wang, Yichen, Xia, Wenfang, Yang, Mingsen, Zhang, Tongxin
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container_end_page 84751
container_issue 88
container_start_page 84748
container_title RSC advances
container_volume 6
creator Shen, Guodong
Zhao, Lingyu
Wang, Yichen
Xia, Wenfang
Yang, Mingsen
Zhang, Tongxin
description A novel cooperatively catalyzed C(sp 3 )-C(sp 2 ) bond C-H activation cross-coupling reaction has been developed. A series of 9-aryl-9 H -xanthenes and 9,9-diaryl-xanthenes were selectively synthesized in moderate to good yields by controlling the reaction time and temperature. A novel palladium-copper catalyzed C(sp 3 )-C(sp 2 ) bond C-H activation cross-coupling reaction has been developed. A series of 9-aryl-9 H -xanthenes and 9,9-diaryl-xanthenes were selectively synthesized in moderate to good yields by controlling the reaction time and temperature.
doi_str_mv 10.1039/c6ra17546e
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title Palladium-copper catalyzed C(sp)-C(sp) bond C-H activation cross-coupling reaction: selective arylation to synthesize 9-aryl-9-xanthene and 9,9-diaryl-xanthene derivatives
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