A greener procedure for the synthesis of [BuN]--[Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine)(NCS)] (N719), a benchmark dye for DSSC applications

A greener procedure for the synthesis of [BuN]--[Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine)(NCS)] (N719), a benchmark dye for DSSC applications

A previously reported protocol for the synthesis of the commercial dye [Bu 4 N] 2 [Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine) 2 (NCS) 2 ] (N719) was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the th...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:RSC advances 2016-06, Vol.6 (61), p.55768-55777
Hauptverfasser: Vierucci, S, Muzzioli, S, Righi, P, Borzatta, V, Gorni, G, Zama, I
Format: Artikel
Sprache:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 55777
container_issue 61
container_start_page 55768
container_title RSC advances
container_volume 6
creator Vierucci, S
Muzzioli, S
Righi, P
Borzatta, V
Gorni, G
Zama, I
description A previously reported protocol for the synthesis of the commercial dye [Bu 4 N] 2 [Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine) 2 (NCS) 2 ] (N719) was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the three synthetic steps. This optimization allowed a 81% reduction of the Sheldon's E factor of the overall process. A previously reported protocol for the synthesis of the commercial dye N719 was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the three synthetic steps.
doi_str_mv 10.1039/c6ra13550a
format Article
fullrecord <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c6ra13550a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c6ra13550a</sourcerecordid><originalsourceid>FETCH-rsc_primary_c6ra13550a3</originalsourceid><addsrcrecordid>eNqFT8FKxDAUDILgonvxLrxjCxtN0jbSo1bFUw_W27IsaZq60dqElxbszZ_wR_wkv8SKikfnMswMwzCEHHN2ylmSn2mJiidZxtQeWQiWSiqYzA_IMoRHNkNmXEi-IG8X8IDG9AbBo9OmGdFA6xCGnYEw9TMFG8C1sL4cyw2l67sxSqlWWLuXiaYfr--_olODoWIlvqza-gltY3sTR2VRxRuIynOexytQUJte754VPkEzfW9dVVUByvvOajVY14cjst-qLpjlDx-Sk5vr--KWYtBbj3ZuT9u_i8l_-ScaP1cN</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A greener procedure for the synthesis of [BuN]--[Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine)(NCS)] (N719), a benchmark dye for DSSC applications</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Vierucci, S ; Muzzioli, S ; Righi, P ; Borzatta, V ; Gorni, G ; Zama, I</creator><creatorcontrib>Vierucci, S ; Muzzioli, S ; Righi, P ; Borzatta, V ; Gorni, G ; Zama, I</creatorcontrib><description>A previously reported protocol for the synthesis of the commercial dye [Bu 4 N] 2 [Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine) 2 (NCS) 2 ] (N719) was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the three synthetic steps. This optimization allowed a 81% reduction of the Sheldon's E factor of the overall process. A previously reported protocol for the synthesis of the commercial dye N719 was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the three synthetic steps.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c6ra13550a</identifier><ispartof>RSC advances, 2016-06, Vol.6 (61), p.55768-55777</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Vierucci, S</creatorcontrib><creatorcontrib>Muzzioli, S</creatorcontrib><creatorcontrib>Righi, P</creatorcontrib><creatorcontrib>Borzatta, V</creatorcontrib><creatorcontrib>Gorni, G</creatorcontrib><creatorcontrib>Zama, I</creatorcontrib><title>A greener procedure for the synthesis of [BuN]--[Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine)(NCS)] (N719), a benchmark dye for DSSC applications</title><title>RSC advances</title><description>A previously reported protocol for the synthesis of the commercial dye [Bu 4 N] 2 [Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine) 2 (NCS) 2 ] (N719) was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the three synthetic steps. This optimization allowed a 81% reduction of the Sheldon's E factor of the overall process. A previously reported protocol for the synthesis of the commercial dye N719 was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the three synthetic steps.</description><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFT8FKxDAUDILgonvxLrxjCxtN0jbSo1bFUw_W27IsaZq60dqElxbszZ_wR_wkv8SKikfnMswMwzCEHHN2ylmSn2mJiidZxtQeWQiWSiqYzA_IMoRHNkNmXEi-IG8X8IDG9AbBo9OmGdFA6xCGnYEw9TMFG8C1sL4cyw2l67sxSqlWWLuXiaYfr--_olODoWIlvqza-gltY3sTR2VRxRuIynOexytQUJte754VPkEzfW9dVVUByvvOajVY14cjst-qLpjlDx-Sk5vr--KWYtBbj3ZuT9u_i8l_-ScaP1cN</recordid><startdate>20160610</startdate><enddate>20160610</enddate><creator>Vierucci, S</creator><creator>Muzzioli, S</creator><creator>Righi, P</creator><creator>Borzatta, V</creator><creator>Gorni, G</creator><creator>Zama, I</creator><scope/></search><sort><creationdate>20160610</creationdate><title>A greener procedure for the synthesis of [BuN]--[Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine)(NCS)] (N719), a benchmark dye for DSSC applications</title><author>Vierucci, S ; Muzzioli, S ; Righi, P ; Borzatta, V ; Gorni, G ; Zama, I</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c6ra13550a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vierucci, S</creatorcontrib><creatorcontrib>Muzzioli, S</creatorcontrib><creatorcontrib>Righi, P</creatorcontrib><creatorcontrib>Borzatta, V</creatorcontrib><creatorcontrib>Gorni, G</creatorcontrib><creatorcontrib>Zama, I</creatorcontrib><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vierucci, S</au><au>Muzzioli, S</au><au>Righi, P</au><au>Borzatta, V</au><au>Gorni, G</au><au>Zama, I</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A greener procedure for the synthesis of [BuN]--[Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine)(NCS)] (N719), a benchmark dye for DSSC applications</atitle><jtitle>RSC advances</jtitle><date>2016-06-10</date><risdate>2016</risdate><volume>6</volume><issue>61</issue><spage>55768</spage><epage>55777</epage><pages>55768-55777</pages><eissn>2046-2069</eissn><abstract>A previously reported protocol for the synthesis of the commercial dye [Bu 4 N] 2 [Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine) 2 (NCS) 2 ] (N719) was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the three synthetic steps. This optimization allowed a 81% reduction of the Sheldon's E factor of the overall process. A previously reported protocol for the synthesis of the commercial dye N719 was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the three synthetic steps.</abstract><doi>10.1039/c6ra13550a</doi><tpages>1</tpages></addata></record>
fulltext fulltext
identifier EISSN: 2046-2069
ispartof RSC advances, 2016-06, Vol.6 (61), p.55768-55777
issn 2046-2069
language
recordid cdi_rsc_primary_c6ra13550a
source Royal Society Of Chemistry Journals 2008-
title A greener procedure for the synthesis of [BuN]--[Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine)(NCS)] (N719), a benchmark dye for DSSC applications
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-30T09%3A41%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20greener%20procedure%20for%20the%20synthesis%20of%20%5BBuN%5D--%5BRu(4-carboxy-4%E2%80%B2-carboxylate-2,2%E2%80%B2-bipyridine)(NCS)%5D%20(N719),%20a%20benchmark%20dye%20for%20DSSC%20applications&rft.jtitle=RSC%20advances&rft.au=Vierucci,%20S&rft.date=2016-06-10&rft.volume=6&rft.issue=61&rft.spage=55768&rft.epage=55777&rft.pages=55768-55777&rft.eissn=2046-2069&rft_id=info:doi/10.1039/c6ra13550a&rft_dat=%3Crsc%3Ec6ra13550a%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true