Synthesis and extensive characterisation of phosphorus doped graphite
The pyrolysis of 1,2-diphosphinobenzene at 800 °C gives a phosphorus-doped graphite (P-DG) with an unprecedented high phosphorus content, ca. 20 at%. In contrast with previously studied boron and nitrogen doped graphite materials, thorough characterisation and analysis of this material demonstrates...
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| Veröffentlicht in: | RSC advances 2016-01, Vol.6 (67), p.6214-62145 |
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| creator | Matthews, Peter D King, Timothy C Glass, Hugh Magusin, Pieter C. M. M Tustin, Gary J Brown, Philip A. C Cormack, Jonathan A García-Rodríguez, Raúl Leskes, Michal Dutton, Siân E Barker, Paul D Grosche, F. Malte Alavi, Ali Grey, Clare P Wright, Dominic S |
| description | The pyrolysis of 1,2-diphosphinobenzene at 800 °C gives a phosphorus-doped graphite (P-DG) with an unprecedented high phosphorus content,
ca.
20 at%. In contrast with previously studied boron and nitrogen doped graphite materials, thorough characterisation and analysis of this material demonstrates that it is extensively disordered and contains substitutional P-atoms along with P&z.dbd;O units in the host graphitic lattice, as well as P
4
molecules trapped between the graphitic sheets. This represents a stabilised form of P
4
, which has been shown to covalently bind to lithium as Li
3
P in this material.
The pyrolysis of 1,2-diphosphinobenzene at 800 °C gives a P-doped graphite with P content
ca.
20 at%. The material contains substitutional P-atoms, P&z.dbd;O units and intercalated, stabilized P
4
molecules, which covalently bind Li as Li
3
P. |
| doi_str_mv | 10.1039/c6ra08639j |
| format | Article |
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ca.
20 at%. In contrast with previously studied boron and nitrogen doped graphite materials, thorough characterisation and analysis of this material demonstrates that it is extensively disordered and contains substitutional P-atoms along with P&z.dbd;O units in the host graphitic lattice, as well as P
4
molecules trapped between the graphitic sheets. This represents a stabilised form of P
4
, which has been shown to covalently bind to lithium as Li
3
P in this material.
The pyrolysis of 1,2-diphosphinobenzene at 800 °C gives a P-doped graphite with P content
ca.
20 at%. The material contains substitutional P-atoms, P&z.dbd;O units and intercalated, stabilized P
4
molecules, which covalently bind Li as Li
3
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ca.
20 at%. In contrast with previously studied boron and nitrogen doped graphite materials, thorough characterisation and analysis of this material demonstrates that it is extensively disordered and contains substitutional P-atoms along with P&z.dbd;O units in the host graphitic lattice, as well as P
4
molecules trapped between the graphitic sheets. This represents a stabilised form of P
4
, which has been shown to covalently bind to lithium as Li
3
P in this material.
The pyrolysis of 1,2-diphosphinobenzene at 800 °C gives a P-doped graphite with P content
ca.
20 at%. The material contains substitutional P-atoms, P&z.dbd;O units and intercalated, stabilized P
4
molecules, which covalently bind Li as Li
3
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ca.
20 at%. In contrast with previously studied boron and nitrogen doped graphite materials, thorough characterisation and analysis of this material demonstrates that it is extensively disordered and contains substitutional P-atoms along with P&z.dbd;O units in the host graphitic lattice, as well as P
4
molecules trapped between the graphitic sheets. This represents a stabilised form of P
4
, which has been shown to covalently bind to lithium as Li
3
P in this material.
The pyrolysis of 1,2-diphosphinobenzene at 800 °C gives a P-doped graphite with P content
ca.
20 at%. The material contains substitutional P-atoms, P&z.dbd;O units and intercalated, stabilized P
4
molecules, which covalently bind Li as Li
3
P.</abstract><doi>10.1039/c6ra08639j</doi><tpages>6</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals |
| title | Synthesis and extensive characterisation of phosphorus doped graphite |
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