Sol gel and ceramic synthesis of SrFeMoWO (0 ≤ ≤ 1) double perovskites series
Preparation methods (ceramic and sol-gel methods) using reducing conditions were optimized for the formation of phase pure double perovskites of Sr 2 FeMo (1− x ) W x O 6 (0 ≤ x ≤ 1) showing enhanced homogeneity and cation ordering for investigating magnetic properties. X-ray diffraction (XRD) revea...
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| Veröffentlicht in: | RSC advances 2016-04, Vol.6 (48), p.4269-4275 |
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| creator | Iranmanesh, M Lingg, M Stir, M Hulliger, J |
| description | Preparation methods (ceramic and sol-gel methods) using reducing conditions were optimized for the formation of phase pure double perovskites of Sr
2
FeMo
(1−
x
)
W
x
O
6
(0 ≤
x
≤ 1) showing enhanced homogeneity and cation ordering for investigating magnetic properties. X-ray diffraction (XRD) revealed a structural transition from tetragonal to monoclinic as W replaces Mo (
x
= 0.5-0.6). The SQUID magnetometry confirmed a ferrimagnetic ground state for Sr
2
FeMoO
6
whereas Sr
2
FeWO
6
shows an antiferromagnetic state. Current results demonstrate that improved preparation methods can enhance the saturation magnetization.
Optimization of pure phase double perovskite series
via
sol-gel methods. |
| doi_str_mv | 10.1039/c6ra03923e |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_c6ra03923e</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c6ra03923e</sourcerecordid><originalsourceid>FETCH-rsc_primary_c6ra03923e3</originalsourceid><addsrcrecordid>eNpjYBAyNNAzNDC21E82K0oE0kbGqUwMnEYGJma6RgZmlhwMvMXFWQZAYGZqaGRmyMkQGJyfo5CemqOQmJeikJxalJibmaxQXJlXkpFanFmskJ-mEFzkluqbH-6voGGg8KhzCRgbaiqk5Jcm5aQqFKQW5ZcVZ2eWpBYrFKcWZaYW8zCwpiXmFKfyQmluBlk31xBnD92i4uT4gqLM3MSiyniE84wJyQMADxxAAQ</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Sol gel and ceramic synthesis of SrFeMoWO (0 ≤ ≤ 1) double perovskites series</title><source>Royal Society Of Chemistry Journals</source><creator>Iranmanesh, M ; Lingg, M ; Stir, M ; Hulliger, J</creator><creatorcontrib>Iranmanesh, M ; Lingg, M ; Stir, M ; Hulliger, J</creatorcontrib><description>Preparation methods (ceramic and sol-gel methods) using reducing conditions were optimized for the formation of phase pure double perovskites of Sr
2
FeMo
(1−
x
)
W
x
O
6
(0 ≤
x
≤ 1) showing enhanced homogeneity and cation ordering for investigating magnetic properties. X-ray diffraction (XRD) revealed a structural transition from tetragonal to monoclinic as W replaces Mo (
x
= 0.5-0.6). The SQUID magnetometry confirmed a ferrimagnetic ground state for Sr
2
FeMoO
6
whereas Sr
2
FeWO
6
shows an antiferromagnetic state. Current results demonstrate that improved preparation methods can enhance the saturation magnetization.
Optimization of pure phase double perovskite series
via
sol-gel methods.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c6ra03923e</identifier><ispartof>RSC advances, 2016-04, Vol.6 (48), p.4269-4275</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Iranmanesh, M</creatorcontrib><creatorcontrib>Lingg, M</creatorcontrib><creatorcontrib>Stir, M</creatorcontrib><creatorcontrib>Hulliger, J</creatorcontrib><title>Sol gel and ceramic synthesis of SrFeMoWO (0 ≤ ≤ 1) double perovskites series</title><title>RSC advances</title><description>Preparation methods (ceramic and sol-gel methods) using reducing conditions were optimized for the formation of phase pure double perovskites of Sr
2
FeMo
(1−
x
)
W
x
O
6
(0 ≤
x
≤ 1) showing enhanced homogeneity and cation ordering for investigating magnetic properties. X-ray diffraction (XRD) revealed a structural transition from tetragonal to monoclinic as W replaces Mo (
x
= 0.5-0.6). The SQUID magnetometry confirmed a ferrimagnetic ground state for Sr
2
FeMoO
6
whereas Sr
2
FeWO
6
shows an antiferromagnetic state. Current results demonstrate that improved preparation methods can enhance the saturation magnetization.
Optimization of pure phase double perovskite series
via
sol-gel methods.</description><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpjYBAyNNAzNDC21E82K0oE0kbGqUwMnEYGJma6RgZmlhwMvMXFWQZAYGZqaGRmyMkQGJyfo5CemqOQmJeikJxalJibmaxQXJlXkpFanFmskJ-mEFzkluqbH-6voGGg8KhzCRgbaiqk5Jcm5aQqFKQW5ZcVZ2eWpBYrFKcWZaYW8zCwpiXmFKfyQmluBlk31xBnD92i4uT4gqLM3MSiyniE84wJyQMADxxAAQ</recordid><startdate>20160427</startdate><enddate>20160427</enddate><creator>Iranmanesh, M</creator><creator>Lingg, M</creator><creator>Stir, M</creator><creator>Hulliger, J</creator><scope/></search><sort><creationdate>20160427</creationdate><title>Sol gel and ceramic synthesis of SrFeMoWO (0 ≤ ≤ 1) double perovskites series</title><author>Iranmanesh, M ; Lingg, M ; Stir, M ; Hulliger, J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c6ra03923e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Iranmanesh, M</creatorcontrib><creatorcontrib>Lingg, M</creatorcontrib><creatorcontrib>Stir, M</creatorcontrib><creatorcontrib>Hulliger, J</creatorcontrib><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Iranmanesh, M</au><au>Lingg, M</au><au>Stir, M</au><au>Hulliger, J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sol gel and ceramic synthesis of SrFeMoWO (0 ≤ ≤ 1) double perovskites series</atitle><jtitle>RSC advances</jtitle><date>2016-04-27</date><risdate>2016</risdate><volume>6</volume><issue>48</issue><spage>4269</spage><epage>4275</epage><pages>4269-4275</pages><eissn>2046-2069</eissn><abstract>Preparation methods (ceramic and sol-gel methods) using reducing conditions were optimized for the formation of phase pure double perovskites of Sr
2
FeMo
(1−
x
)
W
x
O
6
(0 ≤
x
≤ 1) showing enhanced homogeneity and cation ordering for investigating magnetic properties. X-ray diffraction (XRD) revealed a structural transition from tetragonal to monoclinic as W replaces Mo (
x
= 0.5-0.6). The SQUID magnetometry confirmed a ferrimagnetic ground state for Sr
2
FeMoO
6
whereas Sr
2
FeWO
6
shows an antiferromagnetic state. Current results demonstrate that improved preparation methods can enhance the saturation magnetization.
Optimization of pure phase double perovskite series
via
sol-gel methods.</abstract><doi>10.1039/c6ra03923e</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 2046-2069 |
| ispartof | RSC advances, 2016-04, Vol.6 (48), p.4269-4275 |
| issn | 2046-2069 |
| language | |
| recordid | cdi_rsc_primary_c6ra03923e |
| source | Royal Society Of Chemistry Journals |
| title | Sol gel and ceramic synthesis of SrFeMoWO (0 ≤ ≤ 1) double perovskites series |
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