Polypeptides by light: photo-polymerization of N-carboxyanhydrides (NCA)Electronic supplementary information (ESI) available: Experimental procedures, additional MALDI-ToF-MS spectra, real-time FTIR results, light source distance results. See DOI: 10.1039/c6py02018f
The synthesis of polypeptides by N -carboxyanhydride (NCA) photopolymerization is demonstrated. The active initiator cyclohexylamine was produced in situ by the UV-induced breakdown of photoamine generators. Real-time FTIR and MALDI-ToF-MS analyses provide clear evidence for the proposed photoinitia...
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