Self-assembly of amphiphilic macrocycles containing polymeric liquid crystal grafts in solution

The cyclic architecture of amphiphilic side-chain liquid crystalline macrocycles could weaken the order of cholesteryl mesogens, which finally results in the formation of vesicles and other aggregates in solution, while their linear counterparts prefer to self-organize into cylinders within a long r...

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Veröffentlicht in:Polymer chemistry 2016-01, Vol.7 (16), p.2785-2789
Hauptverfasser: Zhou, Feng, Zhang, Zhengbiao, Jiang, Ganquan, Lu, Jinjie, Chen, Xiaofang, Li, Yiwen, Zhou, Nianchen, Zhu, Xiulin
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container_end_page 2789
container_issue 16
container_start_page 2785
container_title Polymer chemistry
container_volume 7
creator Zhou, Feng
Zhang, Zhengbiao
Jiang, Ganquan
Lu, Jinjie
Chen, Xiaofang
Li, Yiwen
Zhou, Nianchen
Zhu, Xiulin
description The cyclic architecture of amphiphilic side-chain liquid crystalline macrocycles could weaken the order of cholesteryl mesogens, which finally results in the formation of vesicles and other aggregates in solution, while their linear counterparts prefer to self-organize into cylinders within a long range ordered lamellar periodicity. Amphiphilic macrocycles containing polymeric liquid crystal side-chains are synthesized facilely, and the topological effects on their solution self-assembly behaviors are investigated, compared with their linear analogues.
doi_str_mv 10.1039/c6py00545d
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Aggregates
Cylinders
Formations
Grafts
Liquid crystals
Macrocyclic compounds
Polymer chemistry
Self assembly
Vesicles
title Self-assembly of amphiphilic macrocycles containing polymeric liquid crystal grafts in solution
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