Synthesis of 2,6-- and 3,3,6-trisubstituted tetrahydropyran-4-ones from Maitland-Japp derived 2-dihydropyran-4-ones: a total synthesis of diospongin B

6-Substituted-2 H -dihydropyran-4-one products of the Maitland-Japp reaction have been converted into tetrahydropyrans containing uncommon substitution patterns. Treatment of 6-substituted-2 H -dihydropyran-4-ones with carbon nucleophiles led to the formation of tetrahydropyran rings with the 2,6- t...

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Veröffentlicht in:	Organic & biomolecular chemistry 2016-07, Vol.14 (28), p.684-6852
Hauptverfasser:	Clarke, Paul A, Nasir, Nadiah Mad, Sellars, Philip B, Peter, Alejandra M, Lawson, Connor A, Burroughs, James L
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