The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)
Herein we show that hydrazine intercalation into 2D titanium carbide (Ti 3 C 2 -based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti 3 C 2 T x layers pre-opening the str...
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| Veröffentlicht in: | Nanoscale 2016-01, Vol.8 (17), p.9128-9133 |
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| container_issue | 17 |
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| container_title | Nanoscale |
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| creator | Mashtalir, O Lukatskaya, M. R Kolesnikov, A. I Raymundo-Piñero, E Naguib, M Barsoum, M. W Gogotsi, Y |
| description | Herein we show that hydrazine intercalation into 2D titanium carbide (Ti
3
C
2
-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti
3
C
2
T
x
layers pre-opening the structure and improving the accessability to active sites. The hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g
−1
in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm.
Herein we show that hydrazine intercalation into 2D titanium carbide (MXene) results in changes in materials surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. |
| doi_str_mv | 10.1039/c6nr01462c |
| format | Article |
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3
C
2
-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti
3
C
2
T
x
layers pre-opening the structure and improving the accessability to active sites. The hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g
−1
in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm.
Herein we show that hydrazine intercalation into 2D titanium carbide (MXene) results in changes in materials surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c6nr01462c</identifier><identifier>PMID: 27088300</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Capacitance ; Chemical Sciences ; Electrodes ; Electrolytes ; Hydrazines ; Intercalation ; Material chemistry ; MATERIALS SCIENCE ; Surface chemistry ; Titanium carbide ; Two dimensional</subject><ispartof>Nanoscale, 2016-01, Vol.8 (17), p.9128-9133</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c506t-18dadb4ad98df899fcd0dc4b0c0ab34b5bc403c0ec7b7b2624a7c1c0dc6b2c433</citedby><cites>FETCH-LOGICAL-c506t-18dadb4ad98df899fcd0dc4b0c0ab34b5bc403c0ec7b7b2624a7c1c0dc6b2c433</cites><orcidid>0000-0001-9712-3987</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,777,781,882,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27088300$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-01898814$$DView record in HAL$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/servlets/purl/1261319$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Mashtalir, O</creatorcontrib><creatorcontrib>Lukatskaya, M. R</creatorcontrib><creatorcontrib>Kolesnikov, A. I</creatorcontrib><creatorcontrib>Raymundo-Piñero, E</creatorcontrib><creatorcontrib>Naguib, M</creatorcontrib><creatorcontrib>Barsoum, M. W</creatorcontrib><creatorcontrib>Gogotsi, Y</creatorcontrib><creatorcontrib>Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)</creatorcontrib><title>The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>Herein we show that hydrazine intercalation into 2D titanium carbide (Ti
3
C
2
-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti
3
C
2
T
x
layers pre-opening the structure and improving the accessability to active sites. The hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g
−1
in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm.
Herein we show that hydrazine intercalation into 2D titanium carbide (MXene) results in changes in materials surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water.</description><subject>Capacitance</subject><subject>Chemical Sciences</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Hydrazines</subject><subject>Intercalation</subject><subject>Material chemistry</subject><subject>MATERIALS SCIENCE</subject><subject>Surface chemistry</subject><subject>Titanium carbide</subject><subject>Two dimensional</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqF0kuLFDEQAOBGFPehF-9K42lXGK08Jp0-LrPqCqOCrOAtJJVqJjKTHpO0sP56M_Y6HoVAHvWlqFBpmmcMXjMQ_RtUMQGTiuOD5pSDhIUQHX94XCt50pzl_B1A9UKJx80J70BrAXDa0O2GWhoGwtKOQ7u588n-CpHaEAsltFtbwhjbOkqFuaQJy5SotdG3aPcWQ7ER6XCXX7flsAvTroaSC57ai4_fKNLlk-bRYLeZnt7P583Xd29vVzeL9ef3H1ZX6wUuQZUF0956J63vtR903w_owaN0gGCdkG7pUIJAIOxc57ji0nbIsBrlOEohzpuXc94xl2ByLY5wg2OM9XmGccUE6yu6nNHGbs0-hZ1Nd2a0wdxcrc3hDJjutWbyJ6v2Yrb7NP6YKBezCxlpu7WRxikbpqFXvJeM_592etkJpkBW-mqmmMacEw3HMhiYQ0vNSn368qelq4pf3Oed3I78kf7tYQXPZ5AyHqP__oT4DbrCpJI</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Mashtalir, O</creator><creator>Lukatskaya, M. 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W ; Gogotsi, Y</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c506t-18dadb4ad98df899fcd0dc4b0c0ab34b5bc403c0ec7b7b2624a7c1c0dc6b2c433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Capacitance</topic><topic>Chemical Sciences</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Hydrazines</topic><topic>Intercalation</topic><topic>Material chemistry</topic><topic>MATERIALS SCIENCE</topic><topic>Surface chemistry</topic><topic>Titanium carbide</topic><topic>Two dimensional</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mashtalir, O</creatorcontrib><creatorcontrib>Lukatskaya, M. R</creatorcontrib><creatorcontrib>Kolesnikov, A. I</creatorcontrib><creatorcontrib>Raymundo-Piñero, E</creatorcontrib><creatorcontrib>Naguib, M</creatorcontrib><creatorcontrib>Barsoum, M. W</creatorcontrib><creatorcontrib>Gogotsi, Y</creatorcontrib><creatorcontrib>Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)</creatorcontrib><creatorcontrib>Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><collection>OSTI.GOV - Hybrid</collection><collection>OSTI.GOV</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mashtalir, O</au><au>Lukatskaya, M. R</au><au>Kolesnikov, A. I</au><au>Raymundo-Piñero, E</au><au>Naguib, M</au><au>Barsoum, M. W</au><au>Gogotsi, Y</au><aucorp>Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)</aucorp><aucorp>Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>8</volume><issue>17</issue><spage>9128</spage><epage>9133</epage><pages>9128-9133</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>Herein we show that hydrazine intercalation into 2D titanium carbide (Ti
3
C
2
-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti
3
C
2
T
x
layers pre-opening the structure and improving the accessability to active sites. The hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g
−1
in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 μm.
Herein we show that hydrazine intercalation into 2D titanium carbide (MXene) results in changes in materials surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>27088300</pmid><doi>10.1039/c6nr01462c</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-9712-3987</orcidid><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Capacitance Chemical Sciences Electrodes Electrolytes Hydrazines Intercalation Material chemistry MATERIALS SCIENCE Surface chemistry Titanium carbide Two dimensional |
| title | The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene) |
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