Cu(ii) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactionsElectronic supplementary information (ESI) available. CCDC 927870. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6nj02193j
An isoindole based Cu( ii ) complex, [ Cu(PICPH)Cl 2 ], was synthesized in situ by reacting copper( ii ) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The compl...
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| creator | Adhikari, Sangita Lohar, Sisir Kumari, Babli Banerjee, Aparna Bandopadhyay, Rajib Matalobos, Jesús Sanmartín Das, Debasis |
| description | An isoindole based Cu(
ii
) complex, [
Cu(PICPH)Cl
2
], was synthesized
in situ
by reacting copper(
ii
) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The complex has a trigonal bipyramid geometry containing both five- and seven-member chelate rings. It shows catecholase-like activity. Interaction of the complex with a bio-relevant antipyrine derivative (
ANNAP
) was studied using fluorescence spectroscopy. DFT studies unfold the energetics associated with PICPH, [
Cu(PICPH)Cl
2
] and the adduct between [
Cu(PICPH)Cl
2
] and
ANNAP
. Antimicrobial activities of the compounds were also studied.
An isoindole based trigonal bipyramidal Cu(
ii
) complex shows catecholase and antimicrobial activities. It interacts with bio-relevant antipyrine derivative. |
| doi_str_mv | 10.1039/c6nj02193j |
| format | Article |
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ii
) complex, [
Cu(PICPH)Cl
2
], was synthesized
in situ
by reacting copper(
ii
) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The complex has a trigonal bipyramid geometry containing both five- and seven-member chelate rings. It shows catecholase-like activity. Interaction of the complex with a bio-relevant antipyrine derivative (
ANNAP
) was studied using fluorescence spectroscopy. DFT studies unfold the energetics associated with PICPH, [
Cu(PICPH)Cl
2
] and the adduct between [
Cu(PICPH)Cl
2
] and
ANNAP
. Antimicrobial activities of the compounds were also studied.
An isoindole based trigonal bipyramidal Cu(
ii
) complex shows catecholase and antimicrobial activities. It interacts with bio-relevant antipyrine derivative.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/c6nj02193j</identifier><language>eng</language><creationdate>2016-11</creationdate><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Adhikari, Sangita</creatorcontrib><creatorcontrib>Lohar, Sisir</creatorcontrib><creatorcontrib>Kumari, Babli</creatorcontrib><creatorcontrib>Banerjee, Aparna</creatorcontrib><creatorcontrib>Bandopadhyay, Rajib</creatorcontrib><creatorcontrib>Matalobos, Jesús Sanmartín</creatorcontrib><creatorcontrib>Das, Debasis</creatorcontrib><title>Cu(ii) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactionsElectronic supplementary information (ESI) available. CCDC 927870. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6nj02193j</title><description>An isoindole based Cu(
ii
) complex, [
Cu(PICPH)Cl
2
], was synthesized
in situ
by reacting copper(
ii
) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The complex has a trigonal bipyramid geometry containing both five- and seven-member chelate rings. It shows catecholase-like activity. Interaction of the complex with a bio-relevant antipyrine derivative (
ANNAP
) was studied using fluorescence spectroscopy. DFT studies unfold the energetics associated with PICPH, [
Cu(PICPH)Cl
2
] and the adduct between [
Cu(PICPH)Cl
2
] and
ANNAP
. Antimicrobial activities of the compounds were also studied.
An isoindole based trigonal bipyramidal Cu(
ii
) complex shows catecholase and antimicrobial activities. It interacts with bio-relevant antipyrine derivative.</description><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFkL1Pw0AMxQMCic-FHclsrURKrikp6Rpa0YkB9sq9ONTlkot8l0L_e66AxIAEky2_n9-zHEUXKhmoJM1vdNask6HK0_V-dKzSLI_zYaYOQq9Gozi5HWVH0Ylz6yRRapyp47246HrMfdC2bg29g60AoaE3YGe5Ka0hKEl4g543NAHnpdO-E7oGjZ70yhp0BIZfCVAHhv32GrDxXLMWu2Q00IptSTyTC0IJS7ZxHXx1Z1CAG0-y27SNm4ahF9uwBte14ZyaGo-yDVBlpcYdBL3p07wPuEE2uDQ0gKK4LyAfju_GyQBmViAAn0Fats6jMfZFsF0F0xI9Bi8o5jMInPUrEqCf0K8QcERw_zifwO-nnkWHFRpH59_1NLqcTZ-Lh1icXrTCdbh28YOnp9HVX_qiLav0P48PgT2Yuw</recordid><startdate>20161128</startdate><enddate>20161128</enddate><creator>Adhikari, Sangita</creator><creator>Lohar, Sisir</creator><creator>Kumari, Babli</creator><creator>Banerjee, Aparna</creator><creator>Bandopadhyay, Rajib</creator><creator>Matalobos, Jesús Sanmartín</creator><creator>Das, Debasis</creator><scope/></search><sort><creationdate>20161128</creationdate><title>Cu(ii) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactionsElectronic supplementary information (ESI) available. CCDC 927870. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6nj02193j</title><author>Adhikari, Sangita ; Lohar, Sisir ; Kumari, Babli ; Banerjee, Aparna ; Bandopadhyay, Rajib ; Matalobos, Jesús Sanmartín ; Das, Debasis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_c6nj02193j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adhikari, Sangita</creatorcontrib><creatorcontrib>Lohar, Sisir</creatorcontrib><creatorcontrib>Kumari, Babli</creatorcontrib><creatorcontrib>Banerjee, Aparna</creatorcontrib><creatorcontrib>Bandopadhyay, Rajib</creatorcontrib><creatorcontrib>Matalobos, Jesús Sanmartín</creatorcontrib><creatorcontrib>Das, Debasis</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adhikari, Sangita</au><au>Lohar, Sisir</au><au>Kumari, Babli</au><au>Banerjee, Aparna</au><au>Bandopadhyay, Rajib</au><au>Matalobos, Jesús Sanmartín</au><au>Das, Debasis</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cu(ii) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactionsElectronic supplementary information (ESI) available. CCDC 927870. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6nj02193j</atitle><date>2016-11-28</date><risdate>2016</risdate><volume>4</volume><issue>12</issue><spage>194</spage><epage>199</epage><pages>194-199</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>An isoindole based Cu(
ii
) complex, [
Cu(PICPH)Cl
2
], was synthesized
in situ
by reacting copper(
ii
) chloride with a pyridine derived ligand, PICPH. The complex was characterized by spectroscopic techniques while its structure was confirmed by single crystal X-ray diffraction analysis. The complex has a trigonal bipyramid geometry containing both five- and seven-member chelate rings. It shows catecholase-like activity. Interaction of the complex with a bio-relevant antipyrine derivative (
ANNAP
) was studied using fluorescence spectroscopy. DFT studies unfold the energetics associated with PICPH, [
Cu(PICPH)Cl
2
] and the adduct between [
Cu(PICPH)Cl
2
] and
ANNAP
. Antimicrobial activities of the compounds were also studied.
An isoindole based trigonal bipyramidal Cu(
ii
) complex shows catecholase and antimicrobial activities. It interacts with bio-relevant antipyrine derivative.</abstract><doi>10.1039/c6nj02193j</doi><tpages>6</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Cu(ii) complex of a new isoindole derivative: structure, catecholase like activity, antimicrobial properties and bio-molecular interactionsElectronic supplementary information (ESI) available. CCDC 927870. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6nj02193j |
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