Hydrogenation of levoglucosenone to renewable chemicalsElectronic supplementary information (ESI) available: Gaussian DFT calculations; 13C NMR of reaction products; CO chemisorption data; synthesis of reaction intermediates; product deconvolution methods; solvent degradation data; and catalyst recycling data. See DOI: 10.1039/c6gc03028a
We have studied the hydrogenation of levoglucosenone (LGO) to dihydrolevoglucosenone (Cyrene), levoglucosanol (Lgol), and tetrahydrofurandimethanol (THFDM) and elucidated the reaction network over supported palladium catalysts. At low temperature (40 ° C) over a Pd/Al 2 O 3 catalyst, LGO is selectiv...
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