A luminescent Pt2Fe spin crossover complexElectronic supplementary information (ESI) available. CCDC 1510868-1510870. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6dt04360g
A heterotrinuclear [Pt 2 Fe] spin crossover (SCO) complex was developed and synthesized employing a ditopic bridging bpp-alkynyl ligand L and alkynyl coordinated Pt II terpy units: [Fe II ( L-Pt II ) 2 ] 2 (BF 4 ) 2 ( 1 ). We identified two different types of crystals of 1 which differ in their mole...
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