Flexible crystals of perovskite-like coordination polymers with a tunable and switchable organic guest: (CH3NH3)2[KFe(CN)6] and (CH3NH3)2[KCo(CN)6]Electronic supplementary information (ESI) available: Crystal structure and thermal properties. CCDC 1508843 and 1508844. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6dt03915d
The crystal structure has been determined for (CH 3 NH 3 ) 2 [KCo(CN) 6 ] at temperatures 100 and 443 K. It crystallizes in the monoclinic space group C 2/ c (LT) and in the cubic one Fm 3&cmb.macr; m (HT). The dielectric response has been investigated for single crystals of pure K 3 [A′(CN) 6 ]...
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