A cooperative pathway for water activation using a bimetallic Pt0-CuI systemElectronic supplementary information (ESI) available. CCDC 1479263 and 1479264. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6dt03305a
A mixture of the platinum(0) complex [Pt(P t Bu 3 ) 2 ] and tetrakis(acetonitrile)copper( i ) hexafluorophosphate in acetone activated a water molecule and gave the hydride platinum( ii ) complex [PtH(CH 3 CN)(P t Bu 3 ) 2 ]PF 6 , 1 , and the hydroxide Cu( i ) species. The crystal structure of compl...
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