A fluorescence study on the complexation of Sm(iii), Eu(iii) and Tb(iii) with tetraalkyldiglycolamides (TRDGA) in aqueous solution, in solid state, and in solvent extractionThis work is an extension of G. Tian's previous research projects at Tsinghua University, Beijing, China and at Lawrence Berkeley National Laboratory, Berkeley, California, USA.Electronic supplementary information (ESI) available: Fig. S1, S2 and Tables S1, S2. CCDC 1434511 (SmLI3(ClO4)3), 1434512 (EuLI3(ClO4)3) and 1434513 (
Tetraalkyldiglycolamide (TRDGA) ligands have potential utilization for the separation of actinide and lanthanide ions in the nuclear industry as chelates in aqueous solution if water-soluble or as extractants in organic solvents if water-insoluble. Here, a spectral titration method is extensively ap...
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