Mechanistic examination of aerobic Pt oxidation: insertion of molecular oxygen into Pt-H bonds through a radical chain mechanism

DFT calculations were performed in an effort to evaluate the mechanism of O 2 insertion into the Pt-H bond of Tp Me 2 Pt IV Me 2 H catalyzed by AIBN or light. Results are consistent with a radical chain mechanism involving H&z.rad; loss to form a Pt III &z.rad; species followed by addition o...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2016-07, Vol.45 (29), p.1165-11656
Hauptverfasser:	Keith, Jason M, Ye, Yixin, Wei, Haochuan, Buck, Matthew R
Format:	Artikel
Sprache:	eng
Schlagworte:	Chains Chemical bonds Equivalence Initiators Insertion Mathematical analysis Platinum Radicals
Online-Zugang:	Volltext
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