Kinetics study of the Ru/C-catalysed hydrogenolysis of polyols - insight into the interactions with the metal surfaceElectronic supplementary information (ESI) available. See DOI: 10.1039/c6cy02104b
The aqueous Ru/C-catalysed hydrogenolysis of xylitol and sorbitol was studied in a temperature range between 393-443 K under 6 MPa H 2 . For the three main reactions, stereoisomerisation, decarbonylation and deoxygenation, kinetic models were formulated and fitted to the experimental data. The obtai...
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