Effect of the C substitution on the ketonic decarboxylation of carboxylic acids over m-ZrO: the role of entropy

The kinetics of the ketonic decarboxylation of linear and branched carboxylic acids over m-ZrO 2 as a catalyst has been investigated. The same apparent activation energy is experimentally determined for the ketonic decarboxylation of both linear pentanoic and branched 2-methyl butanoic acids, while...

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Veröffentlicht in:	Catalysis science & technology 2016-07, Vol.6 (14), p.5561-5566
Hauptverfasser:	Oliver-Tomas, B, Gonell, F, Pulido, A, Renz, M, Boronat, M
Format:	Artikel
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