Synthesis in mesoreactors: Ru(porphyrin)CO-catalyzed aziridination of olefins under continuous flow conditions

The Ru(porphyrin)CO-catalyzed addition of aryl azides to styrenes to afford N -aryl aziridines was successfully performed for the first time in mesoreactors under continuous flow conditions. Mesofluidic technology allowed for a rapid screening of different parameters and a quick identification of th...

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Veröffentlicht in:Catalysis science & technology 2016-01, Vol.6 (13), p.47-474
Hauptverfasser: Rossi, S, Puglisi, A, Benaglia, M, Carminati, D. M, Intrieri, D, Gallo, E
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Sprache:eng
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Zusammenfassung:The Ru(porphyrin)CO-catalyzed addition of aryl azides to styrenes to afford N -aryl aziridines was successfully performed for the first time in mesoreactors under continuous flow conditions. Mesofluidic technology allowed for a rapid screening of different parameters and a quick identification of the optimized reaction conditions. The Ru(porphyrin)CO-catalyzed addition of aryl azides to styrenes to afford N -aryl aziridines was successfully performed for the first time in mesoreactors under continuous flow conditions.
ISSN:2044-4753
2044-4761
DOI:10.1039/c6cy00207b