Consecutive reactions of small, free tantalum clusters with dioxygen controlled by relaxation dynamicsElectronic supplementary information (ESI) available. See DOI: 10.1039/c6cp07631a
The reaction of small cationic tantalum clusters (Ta n + , n = 4-8) with molecular oxygen is studied under multi-collision conditions in the gas phase, and the reaction kinetics are analyzed in order to elucidate underlying mechanisms. Reaction pathways as well as relevant apparent rate constants ar...
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