Au 4f spin-orbit coupling effects in supported gold nanoparticlesElectronic supplementary information (ESI) available: Detailed description of Au/TiO2 catalysts, XRD spectrum of synthesized TiO2, TEM images and Au particle size distributions, ToF-SIMS spectra and sodium impurity. See DOI: 10.1039/c6cp03362h

Using X-ray photoelectron spectroscopy we examine the Au 4f spin-orbit components in Au 4f spectra of nanosized Au particles on a TiO 2 support. In general, the peak ratios of the Au 4f 7/2 and 4f 5/2 excitations are found to deviate from the statistical ratio of 4 : 3 and their linewidths (FWHM) ar...

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Hauptverfasser:	Chenakin, Sergey P, Kruse, Norbert
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