Identification and H(D)-bond energies of C-H(D) Cl interactions in chloride-haloalkane clusters: a combined X-ray crystallographic, spectroscopic, and theoretical study

The cationic (1,3,5-triazapentadiene)Pt II complex [Pt{NH&z.dbd;C(N(CH 2 ) 5 )N(Ph)C(NH 2 )&z.dbd;NPh} 2 ]Cl 2 ([ 1 ]Cl 2 ) was crystallized from four haloalkane solvents giving [ 1 ][Cl 2 (CDCl 3 ) 4 ], [ 1 ][Cl 2 (CHBr 3 ) 4 ], [ 1 ][Cl 2 (CH 2 Cl 2 ) 2 ], and [ 1 ][Cl 2 (C 2 H 4 Cl 2 ) 2...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2016-05, Vol.18 (2), p.1414-14112
Hauptverfasser:	Serebryanskaya, Tatiyana V, Novikov, Alexander S, Gushchin, Pavel V, Haukka, Matti, Asfin, Ruslan E, Tolstoy, Peter M, Kukushkin, Vadim Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Chlorides Clusters Contact Energy use Hydrogen bonds Mathematical analysis Spectroscopy X-rays
Online-Zugang:	Volltext
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