Lower rim dimerization of a calixarene through the encapsulation of sodium ions
Here we report the tail-to-tail dimerization of tetra(carboxymethoxy)calix[4]arene in both solution and solid state phases using ESI-orbitrap UHRMS, 1 H-NMR and single-crystal X-ray diffraction techniques. Three sodium ions are encapsulated into the dimeric structure which is also stabilized by hydr...
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Veröffentlicht in: | CrystEngComm 2016-01, Vol.18 (37), p.6987-6991 |
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creator | Martins, Felipe Terra da Silva, Cleiton Moreira Vasconcelos, Géssica Adriana Gontijo Vaz, Boniek Vieira, Tarcisio da Silva Queiroz Júnior, Luiz Henrique Keng de Fátima, Ângelo |
description | Here we report the tail-to-tail dimerization of tetra(carboxymethoxy)calix[4]arene in both solution and solid state phases using ESI-orbitrap UHRMS,
1
H-NMR and single-crystal X-ray diffraction techniques. Three sodium ions are encapsulated into the dimeric structure which is also stabilized by hydrogen bonds between carboxyl moieties undergoing partial deprotonation.
Here we report the tail-to-tail dimerization of tetra(carboxymethoxy)calix[4]arene in both solution and solid state phases. |
doi_str_mv | 10.1039/c6ce01387b |
format | Article |
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H-NMR and single-crystal X-ray diffraction techniques. Three sodium ions are encapsulated into the dimeric structure which is also stabilized by hydrogen bonds between carboxyl moieties undergoing partial deprotonation.
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H-NMR and single-crystal X-ray diffraction techniques. Three sodium ions are encapsulated into the dimeric structure which is also stabilized by hydrogen bonds between carboxyl moieties undergoing partial deprotonation.
Here we report the tail-to-tail dimerization of tetra(carboxymethoxy)calix[4]arene in both solution and solid state phases.</description><subject>Calixarenes</subject><subject>Diffraction</subject><subject>Dimerization</subject><subject>Encapsulation</subject><subject>Hydrogen bonds</subject><subject>Phases</subject><subject>Sodium</subject><subject>X-rays</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkEtLxDAUhYMoOI5u3AtZilDNnTRpZ6llfMDAbHRd8rh1Im0zJi0-fr3RkdHVORc-LpyPkFNgl8D4_MpIgwx4Weg9MoFcyqxknO__64fkKMYXxiAHYBOyWvo3DDS4jlrXYXCfanC-p76hihrVuncVsEc6rIMfn9cpkWJv1CaO7Y6M3rqxo-mKx-SgUW3Ek9-ckqfbxWN1ny1Xdw_V9TIzfMaHrBEFWADLuWKYG6FSNVJbISyzSkopbAmlbDSzUGqOWs_mBeYzpTVrRJo6Jefbv5vgX0eMQ925aLBtVY9-jDWUuSh5IXie0IstaoKPMWBTb9JcFT5qYPW3tbqS1eLH2k2Cz7ZwiGbH_VnlXwB_agY</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Martins, Felipe Terra</creator><creator>da Silva, Cleiton Moreira</creator><creator>Vasconcelos, Géssica Adriana</creator><creator>Gontijo Vaz, Boniek</creator><creator>Vieira, Tarcisio da Silva</creator><creator>Queiroz Júnior, Luiz Henrique Keng</creator><creator>de Fátima, Ângelo</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>Lower rim dimerization of a calixarene through the encapsulation of sodium ions</title><author>Martins, Felipe Terra ; da Silva, Cleiton Moreira ; Vasconcelos, Géssica Adriana ; Gontijo Vaz, Boniek ; Vieira, Tarcisio da Silva ; Queiroz Júnior, Luiz Henrique Keng ; de Fátima, Ângelo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c323t-f571d11d33a0e4c5a1d3c6bd55d0da6665d8186fb0d18b3ebb297e42abb0f5103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Calixarenes</topic><topic>Diffraction</topic><topic>Dimerization</topic><topic>Encapsulation</topic><topic>Hydrogen bonds</topic><topic>Phases</topic><topic>Sodium</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Martins, Felipe Terra</creatorcontrib><creatorcontrib>da Silva, Cleiton Moreira</creatorcontrib><creatorcontrib>Vasconcelos, Géssica Adriana</creatorcontrib><creatorcontrib>Gontijo Vaz, Boniek</creatorcontrib><creatorcontrib>Vieira, Tarcisio da Silva</creatorcontrib><creatorcontrib>Queiroz Júnior, Luiz Henrique Keng</creatorcontrib><creatorcontrib>de Fátima, Ângelo</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Martins, Felipe Terra</au><au>da Silva, Cleiton Moreira</au><au>Vasconcelos, Géssica Adriana</au><au>Gontijo Vaz, Boniek</au><au>Vieira, Tarcisio da Silva</au><au>Queiroz Júnior, Luiz Henrique Keng</au><au>de Fátima, Ângelo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lower rim dimerization of a calixarene through the encapsulation of sodium ions</atitle><jtitle>CrystEngComm</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>18</volume><issue>37</issue><spage>6987</spage><epage>6991</epage><pages>6987-6991</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>Here we report the tail-to-tail dimerization of tetra(carboxymethoxy)calix[4]arene in both solution and solid state phases using ESI-orbitrap UHRMS,
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H-NMR and single-crystal X-ray diffraction techniques. Three sodium ions are encapsulated into the dimeric structure which is also stabilized by hydrogen bonds between carboxyl moieties undergoing partial deprotonation.
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Calixarenes Diffraction Dimerization Encapsulation Hydrogen bonds Phases Sodium X-rays |
title | Lower rim dimerization of a calixarene through the encapsulation of sodium ions |
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