Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformationElectronic supplementary information (ESI) available: The experimental section, ICP-OES, EDX, XRPD, and water sorption measurements. CCDC 1505012 (1CuZn) and CCDC 1505013 (2CuZn). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6cc07653j
Herein we report a water-induced single-crystal to single-crystal transformation that involves the formation of hetero-bimetallic paddlewheel clusters in coordination polymers. Through this transformation, which involves the cleavage and formation of different coordination bonds, two different Cu( i...
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| creator | Albalad, Jorge Aríñez-Soriano, Javier Vidal-Gancedo, José Lloveras, Vega Juanhuix, Jordi Imaz, Inhar Aliaga-Alcalde, Núria Maspoch, Daniel |
| description | Herein we report a water-induced single-crystal to single-crystal transformation that involves the formation of hetero-bimetallic paddlewheel clusters in coordination polymers. Through this transformation, which involves the cleavage and formation of different coordination bonds, two different Cu(
ii
)-Zn(
ii
) and Cu(
ii
)-Ni(
ii
) paddlewheel units exhibiting a 1 : 1 metal ratio were created.
Hetero-bimetallic paddlewheel clusters in coordination polymers are formed through a water-induced single-crystal to single-crystal transformation. |
| doi_str_mv | 10.1039/c6cc07653j |
| format | Article |
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ii
)-Zn(
ii
) and Cu(
ii
)-Ni(
ii
) paddlewheel units exhibiting a 1 : 1 metal ratio were created.
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ii
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ii
) and Cu(
ii
)-Ni(
ii
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ii
)-Zn(
ii
) and Cu(
ii
)-Ni(
ii
) paddlewheel units exhibiting a 1 : 1 metal ratio were created.
Hetero-bimetallic paddlewheel clusters in coordination polymers are formed through a water-induced single-crystal to single-crystal transformation.</abstract><doi>10.1039/c6cc07653j</doi><tpages>4</tpages></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformationElectronic supplementary information (ESI) available: The experimental section, ICP-OES, EDX, XRPD, and water sorption measurements. CCDC 1505012 (1CuZn) and CCDC 1505013 (2CuZn). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6cc07653j |
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