Enhanced selective adsorption of CO on nitrogen-doped porous carbon monoliths derived from IRMOF-3

The N-doped porous carbon monoliths prepared by direct carbonization of IRMOF-3, through an in situ activation and self-templating process, were found to exhibit significantly enhanced performance for the selective adsorption of CO 2 compared to pristine IRMOF-3. The transformation from the micropor...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-07, Vol.52 (63), p.9757-976
Hauptverfasser: Ding, Shunmin, Dong, Qiaoling, Hu, Jingwei, Xiao, Weiming, Liu, Xiaohui, Liao, Lieqiang, Zhang, Ning
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container_end_page 976
container_issue 63
container_start_page 9757
container_title Chemical communications (Cambridge, England)
container_volume 52
creator Ding, Shunmin
Dong, Qiaoling
Hu, Jingwei
Xiao, Weiming
Liu, Xiaohui
Liao, Lieqiang
Zhang, Ning
description The N-doped porous carbon monoliths prepared by direct carbonization of IRMOF-3, through an in situ activation and self-templating process, were found to exhibit significantly enhanced performance for the selective adsorption of CO 2 compared to pristine IRMOF-3. The transformation from the microporous structure to the meso-macroporous structure opens the pathway for CO 2 to more easily access the nitrogen anchors. The N-doped porous carbon monoliths prepared by direct carbonization of IRMOF-3, through an in situ activation and self-templating process, were found to exhibit significantly enhanced performance for the selective adsorption of CO 2 compared to pristine IRMOF-3.
doi_str_mv 10.1039/c6cc04416f
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title Enhanced selective adsorption of CO on nitrogen-doped porous carbon monoliths derived from IRMOF-3
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